Nucleophilic cyclopropanation of [60]fullerene by the addition–elimination mechanism

Yulya N. Biglova; Akhat G. Mustafin

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Nucleophilic cyclopropanation of [60]fullerene by the addition–elimination mechanism

机译：通过加-消除机理对[60]富勒烯进行亲核环丙烷化

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Information on the synthesis of monofunctionalized methanofullerenes C _(60) obtained by the addition–elimination mechanism is generalized. The main reagents for cyclopropanation, mechanisms and optimal conditions for the processes, and the prospects for practical application of the products are considered.

机译：概述了通过加成-消除机理获得的有关单官能化的甲基富勒烯C _（60）的合成信息。考虑了用于环丙烷化的主要试剂，该方法的机理和最佳条件，以及该产品的实际应用前景。

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《RSC Advances》 |2019年第39期|共71页
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Yulya N. Biglova; Akhat G. Mustafin;
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1. Nucleophilic cyclopropanation of [60]fullerene by the addition-elimination mechanism [J] . Biglova Yulya N., Mustafin Akhat G. RSC Advances . 2019,第39期

机译：通过添加消除机制[60]富勒烯的亲核环丙烷
2. Kinetic study of the reaction of nucleophilic cyclopropanation of C60 fullerene with halogenated maleopimarimide [J] . Biglova Yulya N., Malikova Rauilya N., Petrova Svetlana F., International Journal of Chemical Kinetics . 2019,第5期

机译：C60富勒烯与卤代马达莫西米甲醚的亲核环丙烷反应的动力学研究
3. Synthesis of ether-linked [60]fullerene glycoconjugates by nucleophilic cyclopropanation [J] . Fejes Zsolt, Hadhazi Adam, Ruth Erzsebet, Chemicke Zvesti . 2015,第6期

机译：亲核环丙烷合成醚连接的[60]富勒烯糖缀合物
4. Towards the Synthesis of Enantiomerically Pure 60Fullerene Trisadducts with the Inherently Chiral trans-3, trans-3,trans-3 Addition Pattern [C] . Riala Maria, Chronakis Nikos European Symposium on Organic Chemistry . 2009

机译：以固有的手性反式-3，Trans-3，Trans-3添加图案合成对映体纯的60富勒烯三一体的合成
5. Diels-Alder reactions of [60]fullerene with 1,2,4,5-tetrazines and additions to [60]fullerene-tetrazine monoadducts. [D] . Tetreau, Mark Christopher. 2002

机译：[60]富勒烯与1,2,4,5-四嗪的狄尔斯-阿尔德反应以及向[60]富勒烯-四嗪单加合物的加成反应。
6. Chemistry of Fullerene Epoxides: Synthesis Structure and Nucleophilic Substitution-Addition Reactivity [O] . Yusuke Tajima, Kazumasa Takeshi, Yasuo Shigemitsu, 2012

机译：富勒烯环氧化合物的化学：合成结构和亲核取代-加成反应性。
7. Elimination-Addition Mechanism for Nucleophilic Substitution Reaction of Cyclohexenyl Iodonium Salts and Regioselectivity of Nucleophilic Addition to the Cyclohexyne Intermediate [O] . -1

机译：消除添加机制，用于环己烯型碘鎓盐的亲核取代反应及其亲核中间体的亲核外核选择性
8. Theoretical and experimental investigations of fullerene derivatives: C60H2, C60H4, C 70H2 and C60(CH2)2 [R] . Jacobs, S J, Gillen, K T, Cahill, P A, 1993

机译：富勒烯衍生物的理论和实验研究：C60H2，C60H4，C70H2和C60（CH2）2

Nucleophilic cyclopropanation of [60]fullerene by the addition–elimination mechanism

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