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p-Type CuCrO2 particulate films as the hole transporting layer for CH3NH3PbI3 perovskite solar cells

机译:p型CuCrO2微粒膜作为CH3NH3PbI3钙钛矿太阳能电池的空穴传输层

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CuCrO _(2) with a crystal structure of delafossite is a promising material as a transparent conducting oxide. It shows unique properties, for example, wide band gap, good chemical stability, and p-type carrier transporting character. The oxide layers with delafossite structure have been suggested as hole transporting materials for organic–inorganic CH _(3) NH _(3) PbI _(3) perovskite solar cells. In this study, we fabricated inverted (p–i–n) type planar perovskite solar cells with CuCrO _(2) nanoparticles synthesized by the hydrothermal method and their films were formed by spin-coating without any further heat treatment. The champion device gave a 13.1% of power conversion efficiency and CuCrO _(2) based devices show improved stability in ambient air compared with the standard PEDOT:PSS based perovskite solar cells.
机译:具有铜铁矿晶体结构的CuCrO_(2)是一种有前景的透明导电氧化物。它显示出独特的特性,例如,宽带隙,良好的化学稳定性和p型载流子传输特性。有人建议将具有铜铁矿结构的氧化物层用作有机无机CH_(3)NH_(3)PbI_(3)钙钛矿太阳能电池的空穴传输材料。在这项研究中,我们使用通过水热法合成的CuCrO _(2)纳米粒子制造了倒置(p–i–n)型平面钙钛矿太阳能电池,其薄膜通过旋涂形成,无需进一步热处理。与标准的PEDOT:PSS钙钛矿型太阳能电池相比,冠军型设备的功率转换效率为13.1%,基于CuCrO_(2)的设备在环境空气中显示出更高的稳定性。

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