Molecular chains of coordinated dimolybdenum isonicotinate paddlewheel clusters

Minyuan M. Li; F. James Claire; Marina A. Solomos; Stephanie M. Tenney; Sergei A. Ivanov; Maxime A. Siegler; Thomas J. Kempa

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Molecular chains of coordinated dimolybdenum isonicotinate paddlewheel clusters

机译：配位二钼异烟酸酯叶轮簇的分子链

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A growing focus on the use of coordination polymers for active device applications motivates the search for candidate materials with integrated and optimized charge transport modes. We show herein the synthesis of a linear coordination polymer comprised of Mo _(2) (INA) _(4) (INA = isonicotinate) metal–organic clusters. Single-crystal X-ray structure determination shows that this cluster crystallizes into one-dimensional molecular chains, whose INA-linked Mo _(2) cores engage in alternate axial and equatorial binding motifs along the chain axis. Electron paramagnetic resonance spectra, absorption spectra, and density functional theory calculations show that the aforementioned linear coordination environment significantly modifies the electronic structure of the clusters. This work expands the synthetic foundation for assembly of coordination polymers with tailorable dimensionalities and charge transport properties.

机译：对配位聚合物在有源器件应用中的使用的日益关注，促使人们寻求具有集成和优化电荷传输模式的候选材料。我们在这里显示了由Mo _（2）（INA）_（4）（INA =异烟酸酯）金属-有机簇组成的线性配位聚合物的合成。单晶X射线结构测定表明，该簇结晶为一维分子链，其INA连接的Mo_（2）核沿链轴参与交替的轴向和赤道结合图案。电子顺磁共振谱，吸收谱和密度泛函理论计算表明，上述线性配位环境显着改变了团簇的电子结构。这项工作为具有可调整尺寸和电荷传输性能的配位聚合物组装提供了合成基础。

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《RSC Advances》 |2019年第29期|共4页
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Minyuan M. Li; F. James Claire; Marina A. Solomos; Stephanie M. Tenney; Sergei A. Ivanov; Maxime A. Siegler; Thomas J. Kempa;
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1. Molecular chains of coordinated dimolybdenum isonicotinate paddlewheel clusters [J] . Li Minyuan M., Claire F. James, Solomos Marina A., RSC Advances . 2019,第29期

机译：协调二钼的分子链Isonicotinate PaddleWheel簇
2. 3D coordination framework [Ln(4)(mu(3)-OH)(2)Cu6I5(IN)(8)(OAc)(3)] (IN = isonicotinate): Employing 2D layers of lanthanide wheel clusters and 1D chains of copper halide clusters [J] . Gu XJ, Xue DF Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第13期

机译：3D协调框架[Ln（4）（mu（3）-OH）（2）Cu6I5（IN）（8）（OAc）（3）]（IN =异烟酸酯）：使用2D镧系元素轮簇和1D链卤化铜簇
3. Directed supramolecular assembly of Cu(II)-based "paddlewheels" into infinite 1-D chains using structurally bifunctional ligands [J] . Aakeroy CB, Schultheiss N, Desper J Dalton transactions: An international journal of inorganic chemistry . 2006,第13期

机译：使用结构上的双功能配体将基于Cu（II）的“桨轮”定向到无限一维链的超分子组装
4. The Research of Chain Routing Protocol Based on Coordinate Clustering Strategy in WSNs [C] . Liu Xiaohua, Zheng Gengsheng, Zhang Weidong Information Science and Engineering (ICISE), 2009 . 2009

机译：无线传感器网络中基于坐标聚类策略的链路由协议研究
5. Computational and Experimental Studies of Correlated Dynamics in Molecular Gears, and Crystalline Polarized Rotors in Pillared–Paddlewheel Metal–Organic Frameworks [D] . Liepuoniute, Ieva. 2021

机译：分子齿轮相关动力学的计算与实验研究，以及柱桨式金属有机框架中的晶体偏振转子
6. Supramolecular assemblies of mRNA direct the coordinated synthesis of type I procollagen chains. [O] . A Veis, S J Leibovich, J Evans, 1985

机译：mRNA的超分子组装指导I型原胶原链的协调合成。
7. 3D Coordination Framework Ln4(m3-OH)2Cu6I5(IN)8(OAc)3 (IN = Isonicotinate): Employing 2D Layers of Lanthanide Wheel Clusters and 1D Chains of Copper Halide Clusters [O] . -1

机译：3D协调框架LN4（M3-OH）2Cu6i5（IN）8（OAC）3（in = Isononotinate）：采用2D层镧系轮簇和卤化铜簇的1D链条

Molecular chains of coordinated dimolybdenum isonicotinate paddlewheel clusters

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