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CeO2 facets control: from single (100) to multiple

机译:CeO2方面控制:从单个(100)到多个

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The synthesis of high energy facets and tunable low energy facets was achieved in CeO _(2) films on a SrTiO _(3) substrate by pulsed laser deposition. Three different facets of CeO _(2) with distinctive morphologies appeared consecutively. Firstly, the (100) facet of CeO _(2) , which is the highest energy surface, was grown on the SrTiO _(3) (STO) (100) substrate. The surface energy was decreased gradually with the increase of the laser pulse shots, and the (110) and (111) LEF appeared consecutively. The three different facets presented distinctive morphologies and the interface between each facet could be easily observed by the cross section of Transmission Electron Microscope (TEM) imaging. The interface between the (100) and (110) facet may exhibit excellent oxygen storage capacity, even better than the (100) facet.
机译:通过脉冲激光沉积在SrTiO _(3)衬底上的CeO _(2)薄膜中实现了高能刻面和可调谐低能刻面的合成。具有不同形态的CeO _(2)的三个不同面连续出现。首先,在SrTiO_(3)(STO)(100)衬底上生长CeO _(2)的(100)面,它是最高的能量表面。随着激光脉冲的增加,表面能逐渐降低,(110)和(111)LEF连续出现。三个不同的刻面呈现出独特的形态,每个刻面之间的界面可以通过透射电子显微镜(TEM)成像的横截面轻松观察到。 (100)和(110)小平面之间的界面可表现出优异的储氧能力,甚至比(100)小平面更好。

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