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A general method to fabricate MoO3/C composites and porous C for asymmetric solid-state supercapacitors

机译:制造不对称固态超级电容器的MoO3 / C复合材料和多孔C的通用方法

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MoO _(3) is one of the most promising electrodes for high energy density supercapacitors due to its layered structure, which facilitates the insertion/removal of small ions. However, the commercial recognition of MoO _(3) -based electrodes has been hampered by their low electronic conductivity, poor structural stability and narrow working potential window. A MoO _(3) /C composite (MCs) has been synthesized by a polymerization method followed by calcination of the obtained hydrogel. The obtained MCs electrode exhibits remarkable electrochemical performance in both aqueous (432.5 F g ~(?1) at a current density of 0.5 A g ~(?1) , 100% capacity retention after 10?000 cycles) and all-solid (220.5 F g ~(?1) at 0.5 A g ~(?1) ) systems with porous C as the positive electrode, demonstrating its potential in commercial utilization.
机译:MoO_(3)由于其层状结构而成为用于高能量密度超级电容器的最有希望的电极之一,它有助于小离子的插入/去除。但是,基于MoO_(3)的电极的商业认可已受到其低电导率,较差的结构稳定性和较窄的工作电势窗口的阻碍。通过聚合方法合成MoO_(3)/ C复合物(MCs),然后煅烧所获得的水凝胶。所得的MCs电极在水溶液(432.5 F g〜(?1),电流密度为0.5 A g〜(?1),10?000次循环后100%的容量保持率)和全固态(220.5以多孔碳C为正极的0.5 A g〜(?1)的F g〜(?1)体系,证明了其在商业应用中的潜力。

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