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Tuning the photoluminescence property of carbon dots by ultraviolet light irradiation

机译:通过紫外光调节碳点的光致发光性能

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Tuning of the photoluminescence property of carbon nanodots is realized by surface modification through ultraviolet light irradiation. The photoluminescence of the processed carbon nanodots in the visible region is weakened while that in the ultraviolet region increases significantly. Fourier transform infrared spectroscopy and X-ray photo-electron spectroscopy reveal that the number of surface functional groups decrease significantly after ultraviolet light processing. By examining the electron donating and accepting properties, we confirm that the surface of the carbon nanodots is photoreduced by ultraviolet light, causing a decrease in the number of functional groups as well as emission in the visible region. The temporal behavior of the photoluminescence reveals that the increase of the emission in the ultraviolet region originates from the increased intrinsic state emission of the carbon nanodots.
机译:碳纳米点的光致发光特性的调节是通过紫外线照射进行表面改性而实现的。在可见光区域,已处理的碳纳米点的光致发光减弱,而在紫外光区域中的光致发光显着增加。傅立叶变换红外光谱和X射线光电子能谱表明,紫外线处理后,表面官能团的数量明显减少。通过检查电子的给予和接受性能,我们确认碳纳米点的表面被紫外线光还原,从而导致官能团数量的减少以及可见光区域的发射。光致发光的时间行为表明,紫外区域中发射的增加源自碳纳米点的固有态发射的增加。

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