Olive, castor and linseed oil (oil-in-water) nanoemulsions were prepared using Tween-20, sodium dodecyl sulfate, and cetyltrimethylammonium bromide (0.12 w/w%) with 0.02 w/w% cellulose acetate propionate (CAP), 0.02 w/w% cellulose acetate butyrate (CAB), 6.2 w/w% ethyl acetate, 5.5 w/w% ethanol and 7.8 w/w% glycerol as dispersion agents. To study the dispersion effect of trimesoyl 1,3,5-tridimethyl malonate (TTDMM, 1 ~(st) tier), nanoemulsions were prepared with olive, castor and linseed oil. Their density, viscosity, surface tension and friccohesity measurements at T = (293.15, 303.15, and 315.15) K, hydrodynamic radii, surface excess concentration, surface area per molecule, and antioxidant activities were studied. Dispersion variations of TTDMM on varying surfactant and specific interactions of the hydration spheres and ester moiety of TTDMM with ethyl acetate, ethanol and glycerol linked oil–water–surfactant networks have been established. The variations in physicochemical properties suggest that the oil–TTDMM interaction abilities of the surfactant and co-surfactant moieties in the nanoemulsions cause a hydrophobic segregation. The physicochemical study of both blank and TTDMM loaded nanoemulsions have illustrated the thermodynamic stabilities in terms of hydrophobic–hydrophilic, hydrophilic–hydrophilic, van der Waals and hydrogen bonding interactions.
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机译：使用Tween-20，十二烷基硫酸钠和十六烷基三甲基溴化铵（0.12 w / w％）和0.02 w / w％乙酸丙酸纤维素（CAP），0.02 w制备橄榄，蓖麻和亚麻籽油（水包油）纳米乳剂/ w％乙酸丁酸纤维素（CAB），6.2w / w％乙酸乙酯，5.5w / w％乙醇和7.8w / w％甘油作为分散剂。为了研究均苯三甲酰1,3,5-三甲基丙二酸酯（TTDMM，1〜（st）层）的分散效果，用橄榄，蓖麻和亚麻籽油制备了纳米乳液。研究了它们在T =（293.15、303.15和315.15）K时的密度，粘度，表面张力和摩擦粘度测量结果，流体力学半径，表面过量浓度，每分子表面积和抗氧化活性。已经建立了TTDMM在各种表面活性剂上的分散度变化，以及TTDMM的水合球和酯部分与乙酸乙酯，乙醇和甘油连接的油水表面活性剂网络的特定相互作用。理化性质的变化表明，纳米乳液中表面活性剂和助表面活性剂部分的油与TTDMM相互作用能力导致疏水性偏析。对空白和载有TTDMM的纳米乳剂的物理化学研究已从疏水-亲水，亲水-亲水，范德华力和氢键相互作用方面说明了热力学稳定性。
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