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Adsorbate enrichment on a zeolite surface and assembly of a SERS sensor: a case study with silver nanoparticles and the flavonoid catechin

机译:沸石表面吸附剂的富集和SERS传感器的组装:银纳米颗粒和类黄酮儿茶素的案例研究

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We have studied the adsorption of silver nanoparticles (AgNPs) and catechin on readily available commercial zeolite beads. Both adsorbates became available on the zeolite and were several fold more concentrated after a simple adsorption process, contributing to a 10-times overall increase in the collision probability between the two adsorbates. We were further able to detect AgNP-induced Surface Enhanced Raman Scattering (SERS) of catechin on the zeolite after sequential depositions of AgNPs and catechin on the zeolite using this process. To demonstrate high reproducibility, 93% of the zeolite sensors assembled this way were tested and proved satisfactory, and gave a distinctive catechin SERS signature. Preparation of the zeolite sensor was extremely easy with a nearly 90% yield.
机译:我们已经研究了银纳米颗粒(AgNPs)和儿茶素在容易获得的商业沸石珠上的吸附。两种吸附剂都可以在沸石上使用,并且在简单的吸附过程之后,其浓度要高出几倍,使两种吸附剂之间的碰撞几率总体提高了10倍。使用此过程,我们进一步能够检测到AgNP诱导的儿茶素在沸石上的表面增强拉曼散射(SERS)在沸石上。为了证明其高再现性,对以这种方式组装的93%的沸石传感器进行了测试并证明是令人满意的,并赋予了独特的儿茶素SERS签名。沸石传感器的制备非常容易,产率接近90%。

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