Three promising MOF candidates, UiO-66(Zr), MIL-100(Fe) and MIL-127(Fe) are shaped through granulation with a ρ-alumina binder. Subsequently, changes in the surface characteristics and adsorption performance are evaluated through adsorption microcalorimetry at 303 K with several common probes (N _(2) , CO _(2) , CO, CH _(4) , C _(2) H _(6) , C _(3) H _(8) , C _(3) H _(6) and C _(4) H _(10) ), generating a detailed picture of adsorbate–adsorbent interactions. Vapour adsorption experiments with water and methanol were further used to gauge changes in hydrophobicity caused by the addition of the alumina binder. Upon shaping, a decrease in gravimetric capacity and specific surface area is observed, accompanied by an increased capacity on a volumetric basis, attributed to densification induced by the shaping process, as well as a surprising lack of pore environment changes. However, the magnitude of these effects depends on the MOF, suggesting a high dependence on material structure. Out of the three materials, MIL-127(Fe) shows the least changes in adsorption performance and is highlighted as a promising candidate for further study.
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