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CHEMICAL EVOLUTION OF A CO ICE INDUCED BY SOFT X-RAYS

机译:软X射线诱导的冰的化学演化

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We irradiated a pure carbon monoxide ice with soft X-rays of energies up to 1.2 keV. The experiments were performed using the spherical grating monochromator beamline at the National Synchrotron Radiation Research Center in Taiwan, exploiting both monochromatic (at 0.3 and 0.55 keV) and broader energy (0.25–1.2 keV) fluxes. The infrared spectra of the irradiated ices showed the formation of a number of products such as polycarbon mono- and dioxides CnOm, and chains containing up to 10 carbon atoms. While a gentle increase in the energy absorbed by the ice sample is reflected by an increase in the column densities of newly born species, such correlation breaks down at very high fluxes. In this regime the production yield falls down sharply by about a factor of 100. The refractory residue obtained in the broad energy irradiation is a "compromise" between those obtained with proton irradiation of C3O2 and CO ices in previous experiments. Finally, we discuss the possible implications for space chemistry
机译:我们辐照了纯一氧化碳冰,其软X射线能量高达1.2 keV。实验是使用台湾国家同步辐射研究中心的球形光栅单色仪光束线进行的,该单色线既利用单色(0.3和0.55 keV),又利用了更宽的能量(0.25-1.2 keV)通量。辐照过的冰的红外光谱表明,形成了许多产品,例如一氧化碳和二氧化碳CnOm,以及最多含10个碳原子的链。冰样吸收的能量的缓慢增加反映在新生物种的柱密度增加上,但这种相关性在很高的通量下会破裂。在这种情况下,产量急剧下降了约100倍。在宽能辐照下获得的耐火残渣是在先前实验中用C3O2和CO冰的质子辐照所获得的耐火残渣之间的“折衷”。最后,我们讨论了对空间化学的可能影响

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