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APS -APS March Meeting 2017 - Event - Variation of transition temperatures and residual resistivity ratio in vapor-grown FeSe and Fe(Se,S)

机译:APS -APS 3月会议2017年 - 蒸汽生长的FESE和FE的过渡温度和残余电阻率比的变化 - FEERS(SE,S)

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We report on the vapor growth and physical properties of single-crystalline FeSe and Fe(Se,S). Significant variations of sample morphology resulting from slight modifications of the growth conditions are observed. The superconducting transition temperature, $T_{mathrm c}$, of different FeSe samples varies between 8.8 K and 3 K, and the structural transition temperature, $T_{mathrm s}$, varies between 90 K and 72 K, respectively. We find that those variations cannot be correlated with the sample composition, measured by WDS. Instead, we point out a clear correlation between $T_{mathrm s}$, $T_{mathrm c}$ and disorder, as measured by the residual resistivity ratio. Notably, $T_{mathrm s}$ and $T_{mathrm c}$ are linearly correlated with each otherfootnote{B"ohmer et al., PRB 94, 024526 (2016).}. On the other hand, a small amount of sulfur-substitution suppresses $T_{mathrm s}$ but enhances $T_{mathrm c}$. We will compare and discuss the effects of various perturbations---disorder, chemical substitution and hydrostatic pressure---on the transition temperatures and properties of FeSe.
机译:我们报告单晶FESE和Fe(SE,S)的蒸汽生长和物理性质。观察到由微小修饰产生生长条件产生的样本形态的显着变化。超导转变温度,不同FEES样品的T_ {MATHRM C} $,在8.8 k和3 k之间变化,结构过渡温度$ t_ {mathrm s $,分别在90 k和72 k之间变化。我们发现这些变型不能与由WDS测量的样品组成相关联。相反,我们指出了$ t_ {mathrm s} $,$ t_ {mathrm c} $和紊乱之间的明确相关性,通过剩余电阻率比测量。值得注意的是,$ t_ {mathrm s} $和$ t_ {mathrm c} $与彼此线性相关,{b“ohmer等,prb 94,024526(2016)。}。另一方面,少量硫磺替换抑制$ t_ {mathrm s} $但增强$ t_ {mathrm c} $。我们将比较和讨论各种扰动的影响---紊乱,化学取代和静水压力---在过渡温度和性质上Fese。

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