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Li-ion Battery Separators, Mechanical Integrity and Failure Mechanisms Leading to Soft and Hard Internal Shorts

机译:锂离子电池隔板,机械完整性和失效机制,导致软硬的内部短裤

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Separator integrity is an important factor in preventing internal short circuit in lithium-ion batteries. Local penetration tests (nail or conical punch) often produce presumably sporadic results, where in exactly similar cell and test set-ups one cell goes to thermal runaway while the other shows minimal reactions. We conducted an experimental study of the separators under mechanical loading, and discovered two distinct deformation and failure mechanisms, which could explain the difference in short circuit characteristics of otherwise similar tests. Additionally, by investigation of failure modes, we provided a hypothesis about the process of formation of local "soft short circuits" in cells with undetectable failure. Finally, we proposed a criterion for predicting onset of soft short from experimental data.
机译:分离器完整性是防止锂离子电池内部短路的重要因素。局部穿透试验(指甲或锥形冲头)通常产生大量散态结果,其中在完全相似的细胞和测试设置中,一个电池在另一个电池中进行热失控,而另一个细胞显示最小的反应。我们对机械负荷下的分离器进行了实验研究,并发现了两个不同的变形和失效机制,可以解释其他类似测试的短路特性的差异。另外,通过调查失效模式,我们提供了关于在细胞中形成的局部“软短路”的过程的假设,不可检测失败。最后,我们提出了一种用于预测从实验数据的软短路开始的标准。

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