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Electroless Plating Lead and Lead-Tin on Copper Using an Eco-Friendly Plating Bath

机译:使用生态友好的电镀浴性电镀引线和铜上的引线

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Copper serpentines used in gas heaters are currently coated with lead-tin alloy using hot-dip technology where copper is immersed in molten lead (98%)-Tin at about 400. The major drawback of this technique is the pollution resulted from lead vapors which cause much harm to the labors in the unit. The present work investigates an eco-friendly plating technique to replace the currently used technology. Electroless plating of copper samples with lead or Lead (98%)-Tin alloy is carried out from a plating bath contained lead salt, tin salt, reducing agent and stabilizing agent. The parameters affecting the coating quality such as the plating time, temperature and bath composition were optimized. The chemical analysis and coating morphology of the formed coatings are examined by XRD, SEM and EDS to reach the best bath composition as well as the best conditions to coat copper with lead or lead-tin electrolessly. The electrochemical properties of copper and copper coated samples are also examined using electrochemical impedance spectroscopy.
机译:气体加热器中使用的铜蛇胺目前涂有铅锡合金,使用热浸技术,铜浸入熔融铅(98%) - 锡,约400.该技术的主要缺点是铅蒸汽导致的污染对装置中的劳动力造成很大伤害。目前的工作调查了一种环保电镀技术来取代目前使用的技术。具有铅或铅(98%) - 锡合金的铜样品的化学镀由电镀浴,含铅盐,锡盐,还原剂和稳定剂进行。优化影响涂层质量,例如电镀时间,温度和浴浴组合物的参数。通过XRD,SEM和EDS检查成形涂层的化学分析和涂层形态,以达到最佳浴组合物,以及用铅或铅镀锌涂覆铜的最佳条件。还使用电化学阻抗光谱检查铜和铜涂覆样品的电化学性质。

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