Direct Synthesis of the Phenanthroviridone Skeleton Using a Highly Regioselective Nitroquinone Diels–Alder Reaction

Huangchao Yu; Ellie L. Fought; Theresa L. Windus; George A. Kraus

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Direct Synthesis of the Phenanthroviridone Skeleton Using a Highly Regioselective Nitroquinone Diels–Alder Reaction

机译：使用高度区域选择性的硝基喹啉代尔 - 桤木反应直接合成菲啶骨骨骨架

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A variety of nucleophiles react efficiently with in situ generated nitroquinones. The reaction with substituted resorcinols led to the direct synthesis of the phenanthroviridinone and lagumycin skeleton via a highly regioselective Diels–Alder reaction.

机译：各种亲核试剂用原位产生的硝基醌有效反应。与取代的间苯酚酚的反应导致通过高度区域选择性Diels-Alder反应直接合成菲啶酮和Lagumycin骨架。

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《ACS Omega》 |2020年第16期|共5页
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Huangchao Yu; Ellie L. Fought; Theresa L. Windus; George A. Kraus;
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1. Synthetic studies of GKK1032s: the asymmetric synthesis of the decahydrofluorene skeleton via a novel cyclization of silyl enol ether and sequential retro Diels-Alder and intramolecular Diels-Alder reactions [J] . Hiromi Uchiro, Ryo Kato, Yoshikazu Sakuma Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2011,第47期

机译：GKK1032s的合成研究：通过甲硅烷基烯醇醚的新型环化以及顺序逆向Diels-Alder和分子内Diels-Alder反应的不对称合成十氢芴骨架
2. DIRECT TOTAL SYNTHESES OF FRENOLICIN B AND KALAFUNGIN VIA HIGHLY REGIOSELECTIVE DIELS-ALDER REACTIONS [J] . Kraus GA., Gordon MS., Jensen JH., The Journal of Organic Chemistry . 1995,第5期

机译：高区域选择性Diels-Alder反应直接合成Frenolicin B和Kalafungin
3. Synthesis of highly functionalized [3]dendralenes and their Diels-Alder reactions displaying unexpected regioselectivity [J] . Naidu Gonna Somu, Singh Rekha, Kumar Mukesh, RSC Advances . 2016,第43期

机译：高官能化的合成[3]树枝状和它们的DIELS- alder反应显示出意想不到的区域选择性
4. Cobalt Catalysis in the Gas Phase: Experimental Characterization of Cobalt(I) Complexes as Intermediates in Regioselective Diels-Alder Reactions [C] . Lukas Fiebig, Julian Kuttner, Gerhard Hilt, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2013

机译：气相中的钴催化剂：钴（I）复合物的实验表征作为区域选择性Diels-Alder反应中的中间体
5. Adventures in Lewis acid catalyzed highly hindered Diels-Alder reactions; novel non-Diels-Alder Diels-Alder reaction and its utility for the synthesis of haterumaimide E [D] . Ho, David Gai 2007

机译：路易斯酸的冒险催化了高度阻碍的狄尔斯-阿尔德反应；的非Diels-Alder的新反应Diels-Alder反应及其在合成Haterumaimide E中的用途
6. Direct Synthesis of the Phenanthroviridone SkeletonUsing a Highly Regioselective Nitroquinone Diels–Alder Reaction [O] . Huangchao Yu, Ellie L. Fought, Theresa L. Windus, 2020

机译：苯并蒽醌基骨架的直接合成使用高度区域选择性的硝基醌狄尔斯-阿尔德反应
7. Direct Total Syntheses of Frenolicin B and Kalafungin via Highly Regioselective Diels-Alder Reactions [O] . Kraus, George A., Li, Jun, Gordon, Mark S., 1995

机译：通过高度区域选择性Diels-Alder反应直接合成Frenolicin B和Kalafungin

Direct Synthesis of the Phenanthroviridone Skeleton Using a Highly Regioselective Nitroquinone Diels–Alder Reaction

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