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Co-Combustion Characteristics and Kinetics of Cotton Stalk and Polypropylene Blends

机译:棉秸秆与聚丙烯混合物的共燃烧特性和动力学

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The combustion kinetics of biomass-cotton stalk (CS), polymer-polypro-pylene (PP) and blend of polymer/biomass-polypropylene/cotton stalk blends were examined through thermo gravimetric analysis in this study. The experiments were performed under non-isothermal conditions in the 298 - 873 K temperature interval. The heating rate of this research realized under the air atmosphere was designated as 5 K·min-1. The particle size effect on the combustion behavior of cotton stalk was also studied. A decrease in the maximum rate of decomposition and an increase in the temperature of maximum decomposition with increasing particle size were obtained. Three different models based on the Arrhenius method were used to analyze differential thermo gravimetric data. Blending ratio effects of biomass-cotton stalk and polymer-polypropylene on the combustion kinetics were further explored. Additionally, factors and kinetic parameters were also discussed. Activation energies obtained through the Arrhenius method (n = 1) were much lower than that of polypropylene for all blends. As a result of the research, as the weight percentage of polypropylene in the mixture rises, an increase in activation energy values was observed. The minimum value of the activation energy was calculated with PP/CS with 2/3 blending ratio as 35.8 kJ·mol-1.
机译:通过本研究中的热重分析检查了生物质 - 棉茎(Cs),聚合物 - 聚丙烯(PP),聚合物 - 聚丙烯 - 聚丙烯/棉茎分子的共混物的燃烧动力学。在298-873K温度间隔中的非等温条件下进行实验。在空气气氛下实现的这项研究的加热速率指定为5 k·min-1。还研究了对棉茎燃烧行为的粒度影响。获得了最大分解速率的降低和随着粒度增加的最大分解温度的增加。基于Arrhenius方法的三种不同的模型用于分析差分热重量数据。进一步探索了生物质 - 棉秆和聚合物 - 聚丙烯对燃烧动力学的混合比作用。此外,还讨论了因素和动力学参数。通过Arrhenius方法(n = 1)获得的激活能量远低于所有混合物的聚丙烯的能量。作为研究的结果,随着混合物中聚丙烯的重量百分比上升,观察到激活能量值的增加。用2/3混合比为35.8kJ·mol-1的PP / CS计算活化能量的最小值。

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