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Detection of Bromide Ions in Water Samples with a Nanomolar Detection Limit using a Potentiometric Ion-selective Electrode

机译:使用电位离子选择性电极检测水样中的水样中的溴离子

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This paper presents a robust potentiometric solid-contact ion-selective electrode (ISE) for the rapiddetection of bromide ions (Br-) in water samples. The sensing membrane contains poly (vinyl chloride)(PVC), bis(2-ethylhexyl)sebacate (DOS) and ionophore without a lipophilic ion exchanger, andprovides good potential responses for Br- in the range of 0.010 to 1.0 μM. The calibration curvedemonstrates detection limits of 2.0×10-9 mol/L (3σ) for bromide ions. Moreover, compared withpreviously reported Br--selective ISEs, the proposed ISE offers remarkably improved sensitivity for thedetection of bromide and provides better selectivity coefficients for HPO42-, CH3COO-, NO3-, and Cl-.The proposed sensor is successfully applied for the practical determination of Br- in real watersamples.
机译:本文介绍了一种鲁棒电位的固体接触离子选择电极(ISE),用于在水样中的溴离子(BR-)的快速缩短。传感膜含有聚(氯乙烯)(PVC)(PVC),双(2-乙基己基)Spacate(DOS)和没有亲脂离子交换剂的离子载体,并且在0.010至1.0μm的范围内提供良好的潜在反应。校准曲线术术检测溴离子的2.0×10-9 mol / L(3σ)的限制。此外,与Provously报道的BR选择性相比,所提出的ISE相比,提出了对溴化物的髓中异性显着提高的灵敏度,并为HPO42,CH3COO,NO3-和CL-的更好的选择性系数。所提出的传感器成功应用了实用的传感器真正的水域中的判定。

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