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Li and Na Storage Behaviours of MgFe2O4 Nanoparticles as Anode Materials for Lithium Ion and Sodium Ion Batteries

机译:MGFE 2 O 4 纳米粒子作为锂离子和钠离子电池的阳极材料的Li和Na储存行为

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Porous structured MgFe2O4 particles were successfully prepared via a simple and low-cost route by sol–gel combustion synthesis. The final product was characterized by X-ray diffraction (XRD) and scanningelectron microscopy (SEM). The average diameter of the prepared MgFe2O4 particles was found to beapproximately 41 nm. When used as an anode material of lithium ion batteries (LIBs), MgFe2O4 showedan excellent cycling performance and a fairly high rate performance. The good Li storage performancecan be attributed to the uniform porous structure without impurities that accommodates the strain due tothe volume change in the charge/discharge cycles and expands the active area for lithium ion insertion.Additionally, the Na storage properties of MgFe2O4 as an anode material of sodium ion batteries werestudied, and similar characteristics to those of LIBs were obtained during the discharge/charge cycles,with a high capacity in the initial discharge process but relatively moderate capacity retention comparedto that found in the study of Li storage properties.
机译:通过溶胶 - 凝胶燃烧合成的简单和低成本的途径成功制备多孔结构MgFe2O4颗粒。最终产品的特征在于X射线衍射(XRD)和扫描电子显微镜(SEM)。将制备的MgFe2O4颗粒的平均直径用于BeapproxaximeS 41nm。当用作锂离子电池(LIBS)的阳极材料时,MgFe2O4显示出优异的循环性能和相当高的速率性能。良好的Li储存性能归因于均匀的多孔结构而没有杂质,该杂质容纳由于电荷/放电循环中的体积变化的菌株,并扩展锂离子插入的有源区。加法,MgFe2O4的Na储存性能为阳极材料在放电/电荷循环期间获得了钠离子电池的钠离子电池,并且在放电/电荷循环中获得了类似的特征,初始放电过程中具有高容量,但相对中等的能力保留比较李储物性能研究。

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