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Evolution of Inclusions after Cerium and Titanium Addition in Aluminum Deoxidized Fe-17Cr-9Ni Austenitic Stainless Steel

机译:铈和钛矿床后夹杂物的进化脱氧氧化Fe-17Cr-9NI奥氏体不锈钢

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In this study, the effects of the addition of Ce and Ti on the evolution of inclusions in Al deoxidized Fe-17Cr-9Ni austenitic stainless steel were investigated. When the Ce was added before Ti, Al_(2)O_(3) can be effectively modified into Ce-containing oxides by Ce. With the increase of Ce content, the oxides evolutionary process is as follows: Al_(2)O_(3) → CeAl_(11)O_(18) → CeAlO_(3) → Ce_(2)O_(3). After the addition of Ti, TiN appeared on the surface of oxides except Ce_(2)O_(3). When Ti was added before Ce, due to the simultaneous effects of Ti on the modification of smaller size Al_(2)O_(3) and precipitation of TiN, spherical Al_(2)O_(3)–TiO_(x) inclusion that was completely wrapped by TiN formed. On the other hand, the larger size Al_(2)O_(3) was not significantly modified by Ti, and cannot completely be wrapped by TiN. After Ce was added, the oxides which were not completely wrapped by TiN were modified to Ce-containing oxides. However, Ce could not modify the oxides that were completely wrapped by TiN.
机译:在该研究中,研究了CE和TI对Al脱氧化Fe-17Cr-9NI奥氏体不锈钢中夹杂物的进化的影响。当在Ti之前添加CE时,可以通过CE将AL_(2)O_(3)有效地修改含CE的氧化物。随着CE含量的增加,氧化物进化过程如下:AL_(2)O_(3)→CEAL_(11)O_(18)→CEALO_(3)→CE_(2)O_(3)。添加Ti后,除CE_(2)O_(3)外,锡出现在氧化物表面上。当在CE之前加入TI时,由于TI对较小尺寸AL_(2)O_(3)的修饰和锡的沉淀,球形AL_(2)O_(3)-ti_(x)夹杂物的同时效果完全被锡包裹着。另一方面,Ti未显着修改较大尺寸的AL_(2)O_(3),不能完全被锡包裹。加入Ce之后,将不完全用锡包裹的氧化物改性至含Ce的氧化物。然而,Ce无法修饰锡完全包裹的氧化物。

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