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Rheological Properties and Flow Behaviour of Cement-Based Materials Modified by Carbon Nanotubes and Plasticising Admixtures

机译:碳纳米管改性水泥基材料的流变性能及流动性能及增塑混合物

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In this study, the rheological properties of cement paste modified by a suspension containing both multi-walled carbon nanotubes (MWCNT) and carboxymethyl cellulose (CMC) (MWCNT/CMC suspension) with different types of plasticising admixtures (Pl), such as lignosulphonate (LS), sulfonated naphthalene formaldehyde condensate (NF), and polycarboxylate ether (PCE) were evaluated. The increase in yield stress and plastic viscosity up to 20% was established in the case of the modification of cement-based mixtures by MWCNT in the dosage up to 0.24% by weight of cement (bwoc) without Pl and with LS and NF. The complex modification of cement paste by MWCNT and PCE increases the yield stress and plastic viscosity from the MWCNT dosage of 0.06% and 0.015% bwoc, respectively. The yield stress and plastic viscosity of cement paste with PCE enhanced by 265% and 107%, respectively, in a MWCNT dosage of 0.12% bwoc. MWCNT do not have a significant influence on the flow behaviour index of cement paste; however, in the case of usage of PCE, the shear thickening effect decreased from a MWCNT dosage of 0.03% bwoc. The significant reduction in the volume coefficient of water bleeding by 99, 100, and 83% was obtained with LS, NF, and PCE, respectively, with an increase in MWCNT dosage up to 0.24% bwoc.
机译:在该研究中,通过悬浮液改性的水泥浆料的流变性质,所述悬浮液与多壁碳纳米管(MWCNT)和羧甲基纤维素(CMC)(MWCNT / CMC悬浮液)的不同类型的增塑异化混合物(PL)(如木质素磺酸盐)( LS),评价磺化萘甲醛缩合物(NF)和聚羧酸醚(PCE)。在用MWCNT在没有PL和LS和NF的情况下通过MWCNT的水泥基混合物改变水泥基混合物的情况下,成立屈服应力和塑料粘度高达20%的屈服应力和塑料粘度增加。 MWCNT和PCE的水泥糊的复杂改性分别增加了0.06%和0.015%BWOC的MWCNT剂量的屈服应力和塑料粘度。 PCE的水泥浆料屈服应力和塑料粘度分别增强265%和107%,其MWCNT剂量为0.12%BWOC。 MWCNT对水泥浆料的流动行为指数没有显着影响;然而,在使用PCE的情况下,剪切增稠效果从0.03%BWOC的MWCNT剂量降低。分别用LS,NF和PCE获得99,100和83%的水渗出体积分数的显着降低,其MWCNT剂量增加至0.24%BWOC。

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