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首页> 外文期刊>Journal of Analytical Methods in Chemistry >Study on Blending of Wall Material of the Nonel Tube by CSW/PE-g-MAH
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Study on Blending of Wall Material of the Nonel Tube by CSW/PE-g-MAH

机译:CSW / PE-G-MAH的壬烯管壁材料混合研究

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In order to improve the strength and resistance of ordinary nonel tubes, calcium sulfate whiskers (CSW, treated with silane coupling agent) and maleic anhydride grafted polyethylene (PE-g-MAH) are used to control the wall material of the nonel tube that the blending of the low-density polyethylene was enhanced. The effects of mass fraction of CSW or PE-g-MAH on the tensile properties, interfacial structure, melting and crystallization characteristics, and thermal decomposition behavior of the composite system were studied, and the thermal decomposition kinetics were calculated. The results show that, relative to pure LDPE, the strength of LDPE/CSW (85/15) is increased by 7.58%, and the strength of LDPE/CSW/PE-g-MAH (84/15/1) is increased by 7.58%. The addition of CSW or PE-g-MAH has gradually changed the fracture mode of the LDPE matrix. Thermal analysis shows that CSW can reduce the crystallinity of LDPE. The melting and crystallization characteristics of LDPE/CSW/PE-g-MAH composites have little effect, but the thermal decomposition stability is improved. The kinetic analysis showed that the reaction order (n) was around 1, CSW could improve LDPE/CSW thermal decomposition activation energy, and PE-g-MAH increased the thermal decomposition activation energy of LDPE/CSW/PE-g-MAH.
机译:为了提高普通壬烯管的强度和抗性,使用硫酸钙晶须(用硅烷偶联剂处理的CSW)和马来酸酐接枝聚乙烯(PE-G-MAH)来控制诺尔管的壁材料增强了低密度聚乙烯的混合。研究了CSW或PE-G-MAH对拉伸性能,界面结构,熔融和结晶特性的影响,并计算了复合体系的热分解行为,并计算了热分解动力学。结果表明,相对于纯LDPE,LDPE / CSW(85/15)的强度增加了7.58%,LDPE / CSW / PE-G-MAH(84/15/1)的强度增加7.58%。 CSW或PE-G-MAH的添加逐渐改变了LDPE矩阵的断裂模式。热分析表明,CSW可以减少LDPE的结晶度。 LDPE / CSW / PE-G-MAH复合材料的熔融和结晶特性几乎没有效果,但是改善了热分解稳定性。动力学分析表明,反应顺序(n)约为1,CSW可以改善LDPE / CSW热分解活化能量,PE-G-MAH增加LDPE / CSW / PE-G-MAH的热分解激活能量。

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