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Advanced Energy Materials 2019 Synthesis of vertical graphene network as platform for electrochemical applications - Mineo Hiramatsu - Meijo University

机译:2019年高级能源材料2019垂直石墨烯网络的合成作为电化学应用的平台 - Mineo Hiramatsu - Meijo大学

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Graphene based materials, for example, carbon nanotube and graphene sheet itself have a wide scope of potential applications. Among this grapheme based materials, carbon nano walls (CNWs) are self-upheld organization of few-layer graphenes standing vertically on the substrate to shape 3- dimensional structure. The mazelike design of CNWs with huge surface region graphene planes would be valuable as anodes for vitality stockpiling gadgets, electrochemical and biosensors and framework for cell refined. CNWs and related materials can be blended by a few plasma upgraded concoction fume testimony (PECVD) strategies on warmed substrates utilizing CH4 and H2 blends. Control of CNW structures including dividing between adjoining nano walls and crystallinity is noteworthy for the common sense applications. Besides, surface functionalization including surface end and design with synergist metal nanoparticles ought to be set up. We report the current status of manufacture and structure control of CNWs utilizing a few PECVD methods. Additionally, CNW surface was enlivened with Pt nanoparticles by the decrease of chloroplatinic corrosive or by the metal-natural concoction affidavit utilizing supercritical liquid. We likewise report the exhibitions of hydrogen peroxide (H2O2) sensor and energy component, where CNW terminal was utilized. For the H2O2 detecting application, CNWs were developed on carbon fiber paper (CFP) utilizing PECVD with CH4/Ar blend to build the surface zone. At that point, CNW surface was enlivened with Pt nanoparticles by the decrease of H2PtCl6 in arrangement.
机译:石墨烯基材料,例如,碳纳米管和石墨烯片本身具有广泛的潜在应用。在这种基于标记的材料中,碳纳米壁(CNWS)是在基板上垂直站立的几层石墨的自追踪组织,以形状3尺寸结构。具有巨大的表面积石墨烯平面的CNWS的MAZELIKE设计将有价值的是用于活力储存小工具,电化学和生物传感器和细胞精制框架的阳极。 CNWS和相关材料可以通过少量血浆升级的混合物烟雾证词(PECVD)策略在利用CH4和H2混合物的温热的基材上进行混合。控制CNW结构,包括除邻接纳米壁和结晶度之间,对于常识应用是值得注意的。此外,表面官能化包括表面端和设计,具有增量金属纳米粒子应该设立。我们报告了利用几种PECVD方法的CNWS制造和结构控制的当前状态。另外,通过利用超临界液体的氯铂腐蚀性或通过金属 - 天然混合物副磷脂的降低,用Pt纳米颗粒生成CNW表面。我们同样地报告使用CNW末端的过氧化氢(H2O2)传感器和能量分量的展览。对于H2O2检测应用,利用CH4 / AR混合物的PECVD在碳纤维纸(CFP)上开发CNW,以构建表面积。此时,CNW表面与Pt纳米颗粒的加热通过H2PTCL6的布置减少而活化。

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