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Selective detection of trinitrophenol by a Cd(ii)-based coordination compound

机译:通过CD(II)基于CD(II)的配位化合物选择性检测Trinitrophenol

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A Cd( II )-based coordination compound, [CdI _(2) (4-nvp) _(2) ] ( 1 ), has been synthesized using CdI _(2) and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of other nitroaromatics. Therefore, this material may be used for anti-terrorist activities in the detection of explosive materials as well as in the recognition of TNP in analytical laboratories.
机译:基于CDI(2)(4-NVP)_(2)](1)的CD(II)的配位化合物已经使用CDI _(2)和单常液N-供体配体4-(1-萘基吡啶基)吡啶(4-NVP)。固态超分子架构的特征在于X射线晶体学。急性热稳定性和优异的相纯度诱使我们用于材料应用。有趣的是,化合物1在其他硝基甲族化合物存在下对三硝基苯酚(TNP)具有高选择性。因此,这种材料可用于检测爆炸性材料中的抗恐怖活动以及在分析实验室中的TNP识别。

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