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Investigation of the structure and performance of Li[Li0.13Ni0.305Mn0.565]O2 Li-rich cathode materials derived from eco-friendly and simple coating techniques

机译:研究了Li [Li0.13Ni0.305MN0.565]富锂富型阴极材料的结构和性能

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摘要

Constructing uniform nanoceramic coating layers is a well-known challenge in the field of coating materials. Herein, Al _(2) O _(3) -coated Li[Li _(0.13) Ni _(0.305) Mn _(0.565) ]O _(2) (LLNM) Li-rich cathode materials are successfully prepared through a dry prilling coating (DPC) method. The structures and electrochemical performances of the Al _(2) O _(3) -coated products are systematically examined. Typically, the cycling stability is enhanced and voltage degradation upon cycling is reduced, benefiting from the unique and controllable nano-sized Al _(2) O _(3) coating layer. Moreover, metal ion dissolution is avoided when using the DPC method, which is eco-friendly and suitable for large scale production.
机译:构建均匀的纳米陶瓷涂层是涂料领域的众所周知的攻击。在此,Al _(2)O _(3) - 涂覆的Li [Li _(0.13)Ni _(0.305)Mn _(0.565)] O _(2)(LLNM)通过A成功制备富氢的阴极材料干燥仔细涂层(DPC)方法。系统地检查了Al _(2)O _(3)包装产品的结构和电化学性能。通常,循环稳定性增强,并且减少了循环时的电压劣化,受益于独特和可控的纳米尺寸的Al _(2)O _(3)涂层。此外,使用DPC方法时,避免了金属离子溶解,这是生态友好的,适用于大规模生产。

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