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Electrospun silk fibroin/TiO2 mats. Preparation, characterization and efficiency for the photocatalytic solar treatment of pesticide polluted water

机译:Electromun丝绸纤维素/ TiO2垫。杀虫剂污染水的光催化太阳能处理的制备,表征和效率

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The photocatalytic properties of silk fibroin (SF) incorporating TiO _(2) nanoparticles using an electrospinning technique were examined. Electrospun SF/TiO _(2) mats were successfully prepared and characterized by different techniques (XRD, FE-SEM, XPS, XDS, FTIR and BET). The photocatalytic efficiency of these materials were assessed by their ability to degrade four pesticides (boscalid, hexythiazox, pyraclostrobin and trifloxystrobin) in water exposed to solar irradiation. The effect of catalyst loading on the disappearance kinetics of the different pesticides was studied in order to determine the maximum degradation efficiency. The degradation rate significantly increases upon adding the TiO _(2) . However, no significant differences ( p < 0.05) were observed when the TiO _(2) loading was increased from 25 to 50 mg for most compounds. Thus, SF mats with 25 mg of TiO _(2) were selected. Therefore, a new and simple approach to produce materials with photocatalytic activity, safety and potential application in the purification of water contaminated by pesticides has been developed.
机译:检查了使用静电纺丝技术的含有TiO _(2)纳米颗粒的丝素蛋白(SF)的光催化性质。 Electrom淘SF / TiO _(2)垫被成功制备并以不同的技术(XRD,FE-SEM,XPS,XDS,FTIR和BET)为特征。通过它们在暴露于太阳照射的水中降解四种农药(蒙散,己二唑,丙杂酚和三氟叶蛋白)的能力来评估这些材料的光催化效率。研究了催化剂负载对不同杀虫剂消失动力学的影响,以确定最大的降解效率。在添加TiO _(2)时,降解速率显着增加。然而,当TiO _(2)载荷从25至50mg增加到大多数化合物时,没有观察到显着差异(P <0.05)。因此,选择了具有25mg TiO _(2)的SF垫。因此,已经开发出一种新的和简单的方法,可以制定具有光催化活性,安全性和潜在应用在受杀虫剂污染的水中的光催化活性,安全性和潜在应用的材料。

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