Organic–inorganic nanocrystal reductase to promote green asymmetric synthesis

Kotchakorn T.sriwong; Afifa Ayu Koesoema; Tomoko Matsuda

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Organic–inorganic nanocrystal reductase to promote green asymmetric synthesis

机译：有机 - 无机纳米晶体还原酶，促进绿色不对称合成

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An acetophenone reductase from Geotrichum candidum ( Gc APRD) was immobilized by the organic–inorganic nanocrystal method. The Gc APRD nanocrystal presented improved stability and recyclability compared with those of the free Gc APRD. Moreover, the Gc APRD nanocrystal reduced broad kinds of ketones with excellent enantioselectivities to produce beneficial chiral alcohols such as ( S )-1-(3′,4′-dichlorophenyl)ethanol with >99% yield and >99% ee. The robust and versatile properties of the Gc APRD nanocrystal demonstrated an approach to promote green asymmetric synthesis and sustainable chemistry.

机译：通过有机 - 无机纳米晶体法固定来自GeoTrichum Candidum（GC APRD）的苯乙酮还原酶。与免费的GC APRD相比，GC APRD纳米晶体呈现出改善的稳定性和可回收性。此外，GC APRD纳米晶体具有优异的对映选择性的酮类较低，以产生有益的手性醇，例如（S）-1-（3'，4'-二氯苯基）乙醇，其具有> 99％收率和> 99％EE。 GC APRD纳米晶体的鲁棒和通用性质表明了一种促进绿色不对称合成和可持续化学的方法。

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《RSC Advances》 |2020年第51期|共8页
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Kotchakorn T.sriwong; Afifa Ayu Koesoema; Tomoko Matsuda;
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1. Organic-inorganic nanocrystal reductase to promote green asymmetric synthesis [J] . Tsriwong Kotchakorn, Koesoema Afifa Ayu, Matsuda Tomoko RSC Advances . 2020,第51期

机译：有机 - 无机纳米晶体还原酶，促进绿色不对称合成
2. Molecular Iodine for a General Synthesis of Binary and Ternary Inorganic and Hybrid Organic - Inorganic Iodide Nanocrystals [J] . Akkerman Quinten A., Martinez-Sarti Laura, Goldoni Luca, Chemistry of Materials: A Publication of the American Chemistry Society . 2018,第19期

机译：二元合成的分子碘和三元无机和杂种有机 - 无机碘化物纳米晶体的一般合成
3. Synthesis of ligand-free, large scale with high quality all-inorganic CsPbI3 and CsPb2Br5 nanocrystals and fabrication of all-inorganic perovskite solar cells [J] . Murugadoss Govindhasamy, Thangamuthu Rangasamy, Kumar Sakkarapalayam Murugesan Senthil, Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2019,第期

机译：无高品质的无机CSPBI3和CSPB2BR5纳米晶体的合成，大规模的韧带的大规模和全无机钙钛矿太阳能电池的制备
4. Plasma synthesis of silicon nanocrystals and application to organic/inorganic hybrid photovoltaics [C] . Yi Ding, Ryan Gresback, Ken Okazaki, The 22nd International photovoltaic science and engineering conference . 2012

机译：硅纳米晶的等离子体合成及其在有机/无机杂化光伏中的应用
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机译：镧系元素掺杂无机纳米晶体的合成，表征和光谱学；上转换纳米晶体的辐射通量和绝对量子产率测量，以及使用综合优化的线性响应纳米闪烁体制作的光纤辐射探测器。
6. Effect of Inorganic and Organic Carbon Enrichments (DIC and DOC) on the Photosynthesis and Calcification Rates of Two Calcifying Green Algae from a Caribbean Reef Lagoon [O] . Friedrich W. Meyer, Nadine Schubert, Karen Diele, 2011

机译：无机和有机碳富集（DIC和DOC）对来自加勒比礁湖的两种钙化绿藻光合作用和钙化速率的影响
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机译：镧系掺杂无机纳米晶的合成，表征和光谱分析;上转换纳米晶体的辐射通量和绝对量子产额测量，以及利用综合优化的线性响应纳米闪烁体制造光纤辐射探测器

Organic–inorganic nanocrystal reductase to promote green asymmetric synthesis

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