Novel light-emitting clays with structural Tb3+ and Eu3+ for chromate anion detection

Stefano Marchesi; Chiara Bisio; Fabio Carniato

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Novel light-emitting clays with structural Tb3+ and Eu3+ for chromate anion detection

机译：具有结构TB3 +和EU3 +的新型发光粘土，用于铬酸根阴离子检测

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Tb ~(3+) and Eu ~(3+) ions were encapsulated for the first time in the inorganic layers of a synthetic saponite clay following a one-pot synthetic approach. The co-presence of the two metal ions led to tuneable light-emitting properties, promoted by an efficient Tb ~(3+) → Eu ~(3+) energy transfer and enhanced Stokes shift character. To our knowledge, the so-prepared luminescent material was tested for the first time as an optical sensor for the detection of chromate anions in water.

机译：在单盆合成方法之后，在合成皂石粘土的无机层中首次封装Tb〜（3+）和Eu〜（3+）离子。两个金属离子的共同存在导致可调谐的发光性能，通过有效的Tb〜（3+）→Eu〜（3+）能量转移和增强的斯托克斯换档特征促进。据我们所知，如此制备的发光材料作为光学传感器测试，用于检测水中的铬酸盐阴离子。

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《RSC Advances》 |2020年第50期|共7页
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Stefano Marchesi; Chiara Bisio; Fabio Carniato;
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1. Novel light-emitting clays with structural Tb(3+)and Eu(3+)for chromate anion detection [J] . Marchesi Stefano, Bisio Chiara, Carniato Fabio RSC Advances . 2020,第50期

机译：具有结构TB（3+）和EU（3+）的新型发光粘土，用于铬酸盐阴离子检测
2. Energy transfer and luminescence properties of KZnF3: Ln(3+) (Ln(3+) = Eu3+, Tb3+, Eu3+/Tb3+, Eu3+/Tb3+/Tm3+) phosphors [J] . Di Keshu, Li Xue, Jing Xinda, Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2016,第Null期

机译：KZnF3：Ln（3+）（Ln（3+）= Eu3 +，Tb3 +，Eu3 + / Tb3 +，Eu3 + / Tb3 + / Tm3 +）荧光粉的能量转移和发光特性
3. Photoluminescence and energy transfer properties of a novel molybdate KBaY(MoO4)(3):Ln(3+) (Ln(3+) = Tb3+, Eu3+, Sm3+, Tb3+/Eu3+, Tb3+/Sm3+) as a multi-color emitting phosphor for UV w-LEDs [J] . Li Kai, Van Deun Rik Dalton transactions: An international journal of inorganic chemistry . 2018,第20期

机译：新型钼酸盐KBAY（MOO4）（3）（3）（3）（LN（3+）= TB3 +，EU3 +，SM3 +，TB3 + / EU3 +，TB3 + / SM3 +，TB3 + / SM3 +）的光致发光和能量转移性能作为多色发光磷光体对于UV W-LED
4. Structures and luminescence of mixed lanthanide(Tb3+,Eu3+)coordination CMC and HPCMC [C] . Weipeng Liang, Jun Ye, Jian Xiong 第五届制浆造纸新技术国际研讨会（ISETPP）暨第三届国际造纸与环境学术大会（IPEC）论文集 . 2016

机译：镧系元素（Tb3 +，Eu3 +）配位CMC和HPCMC的结构和发光
5. Photoluminescence, Dual-donor Energy Transfer and Single X-ray Crystallographic Studies of Eu3+ and Tb3+ complexes with pyridines and triazaphosphaadamantane oxide (TPAO) ligands. [D] . Forcha, Derick Akaju. 2013

机译：Eu3 +和Tb3 +配合物与吡啶和三氮杂磷金刚烷氧化物（TPAO）配体的光致发光，双供体能量转移和单X射线晶体学研究。
6. Photo-modulated wide-spectrum chromism in Eu3+ and Eu3+/Tb3+ photochromic coordination polymer gels: application in decoding secret information [O] . Parul Verma, Ashish Singh, Tapas Kumar Maji 2021

机译：EU3 +和EU3 + / TB3 +光致变色协调聚合物凝胶中的光调制宽频谱色谱：在解码秘密信息中的应用
7. Estudo espectroscópico de complexos de Eu3+, Tb3+ E Gd3+ com ligantes derivados de ácidos dicarboxílicos Spectroscopic study of the Eu3+, Tb3+ and Gd3+ complexes with ligands derived from dicarboxylic acids [O] . Patrícia P. Lima, Oscar L. Malta, Severino Alves Júnior 2005

机译：Eu3 +，Tb3 + E Gd3 +与二元羧酸衍生的配体的光谱学研究Eu3 +，Tb3 +和Gd3 +与二元羧酸衍生的配体的光谱学研究

Novel light-emitting clays with structural Tb3+ and Eu3+ for chromate anion detection

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