Sc3N@Ih-C80 based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation

Rubén Caballero; Luis David Servián; Habtom B. Gobeze; Olivia Fernandez-Delgado; Luis Echegoyen; Francis DSouza; Fernando Langa

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Sc3N@Ih-C80 based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation

机译：SC3N @ IH-C80的供体π缀合物：噻吩垫片在促进超快激励状态电荷分离中的作用

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Light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc _(3) N@ I _( h ) -C _(80) donor–acceptor conjugate and its C _(60) analog, triphenylamine–thiophene-C _(60) conjugate is reported, and the significance of the thiophene spacer in promoting electron transfer events is unraveled.

机译：光诱导的电荷分离在新合成的三苯胺 - 噻吩-Sc_（3）N _（3）N = I _（H）-C -C _（80）供体 - 受体缀合物及其C _（60）类似物，三苯胺 - 噻吩-C_（报道了60）缀合物，并且噻吩间隔物在促进电子转移事件方面的意义被解开。

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《RSC Advances》 |2020年第34期|共6页
作者
Rubén Caballero; Luis David Servián; Habtom B. Gobeze; Olivia Fernandez-Delgado; Luis Echegoyen; Francis DSouza; Fernando Langa;
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1. Sc3N@I-h-C(80)based donor-acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation [J] . Caballero Ruben, Servian Luis David, Gobeze Habtom B., RSC Advances . 2020,第34期

机译：SC3N @ I-H-C（80）的供体占主缀合物：噻吩垫片在促进超快激励状态电荷分离方面的作用
2. Quadrupolar Cyclopenta[hi]aceanthrylene-Based Electron Donor-Acceptor-Donor Conjugates: Charge Transfer versus Charge Separation [J] . Schierl Christoph, Alex Wiebke, Mateo Luis M., Angewandte Chemie . 2019,第41期

机译：Quadrupolar cyclopenta [HI]加法萘基电子供体 - 受体 - 供体缀合物：电荷转移与电荷分离
3. Ultrafast Photoinduced Charge Separation Leading to High-Energy Radical Ion-Pairs in Directly Linked Corrole-C-60 and Triphenylamine-Corrole-C-60 Donor-Acceptor Conjugates [J] . Sudhakar Kolanu, Gokulnath Sabapathi, Giribabu Lingamallu, Chemistry, an Asian journal . 2015,第12期

机译：超快光诱导电荷分离导致直接连接的Corrole-C-60和三苯胺-Corrole-C-60供体-受体共轭物中的高能自由基离子对。
4. Quadrupolar CyclopentaHiAceanthrylene-Based Electron Donor-Acceptor-Donor Conjugates: Charge Transfer Versuscharge Separation [C] . Dirk M. Guldi Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

机译：Quadrupolar Cyclopenta HI加法萘基的电子供体 - 受体 - 供体缀合物：电荷转移versums分离
5. Donor -acceptor methods for band gap reduction in conjugated polymers: The role of electron rich donor heterocycles [D] . Thomas, Christopher A. 2001

机译：降低共轭聚合物中带隙的施主-受主方法：富电子施主杂环的作用
6. Charge stabilization via electron exchange: excited charge separation in symmetric central triphenylamine derived dimethylaminophenyl–tetracyanobutadiene donor–acceptor conjugates [O] . Indresh S. Yadav, Ajyal Z. Alsaleh, Rajneesh Misra, 2021

机译：通过电子交换充电稳定：对称的激发电荷分离中央三苯胺衍生二甲基氨基苯基 - 四环丁二烯供体缀合物
7. Frontispiece: Quadrupolar Cyclopenta hi aceanthrylene‐Based Electron Donor‐Acceptor‐Donor Conjugates: Charge Transfer versus Charge Separation [O] . Christoph Schierl, Wiebke Alex, Luis M. Mateo, 2019

机译：正面：Quadrupolar Cyclopenta HI加法萘基电子供体 - 受体 - 供体缀合物：电荷转移与电荷分离

Sc3N@Ih-C80 based donor–acceptor conjugate: role of thiophene spacer in promoting ultrafast excited state charge separation

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