Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions

Yan Zhang; Jiangli Lou; Min Li; Zhenbo Yuan; Yijian Rao

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Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions

机译：Emodin作为一种新型有机光催化剂，用于在温和条件下选择性氧化硫化物

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Herein, we have developed naturally-occurring Emodin , which is commercially available at low-cost, as a novel organic photocatalyst for the first time. Emodin was successfully employed in the selective oxidation of sulfides promoted by visible-light, delivering valuable sulfoxides with high efficiency. Mechanistic investigations suggested both single-electron transfer (SET) and energy transfer (EnT) pathways might be involved in the oxidation reaction.

机译：在此，我们开发了天然存在的大蛋白，其在低成本中可商购获得，作为新型有机光催化剂首次。成功地用于通过可见光促进的硫化物选择性氧化成式氧化，效率高递送有价值的亚砜。机械研究表明，氧化反应可能涉及单电子转移（设定）和能量转移（ENT）途径。

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《RSC Advances》 |2020年第34期|共4页
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Yan Zhang; Jiangli Lou; Min Li; Zhenbo Yuan; Yijian Rao;
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1. Emodinas a novel organic photocatalyst for selective oxidation of sulfides under mild conditions [J] . Zhang Yan, Lou Jiangli, Li Min, RSC Advances . 2020,第34期

机译：Emodinas一种新型有机光催化剂，用于在温和条件下选择性氧化硫化物
2. Dinitrogen tetroxide complexes of iron(III) and copper(II) nitrates as new versatile reagents for organic synthesis. Efficient and selective oxidation of sulfides to their corresponding sulfoxides under mild conditions. [J] . Firouzabadi H., Zolfigol MA., Iranpoor N. Synthetic Communications . 1998,第2期

机译：硝酸铁（III）和硝酸铜（II）的四氧化二氮配合物，是有机合成的新型多功能试剂。在温和条件下将硫化物有效且选择性地氧化为相应的亚砜。
3. Zeolite nanoparticles (H-ZSM5) as a highly efficient, green, and reusable heterogeneous catalyst for selective oxidation of sulfides to sulfoxides under mild conditions [J] . Rostami Amin, Saedmocheshi Noosheen, Shirvandi Zeinab Comptes Rendus Chimie . 2018,第9期

机译：沸石纳米颗粒（H-ZSM5）作为高效，绿色和可重复使用的非均相催化剂，用于在温和条件下选择性氧化硫化物至亚砜
4. Biomimetic Oxidation of Sulfides Based on FeIII Porphyrin under the Mild Conditions [C] . Zhou Xinrui, Chen Xian, Wang Yi, Biomedical Engineering and Biotechnology (iCBEB), 2012 International Conference on . 2012

机译：FeIII卟啉在温和条件下仿生氧化硫化物
5. Metal Oxides as Photocatalysts for Selective Oxidations [D] . Proctor, Aaron. 2020

机译：金属氧化物作为选择性氧化的光催化剂
6. Graphene Oxide Foam Supported Titanium(IV): Recoverable Heterogeneous Catalyst for Efficient Selective Oxidation of Arylalkyl Sulfides to Sulfoxides Under Mild Conditions [O] . Qinghe Wang, Wenxi Ma, Qiaolin Tong, -1

机译：石墨烯氧化物泡沫负载的钛（IV）：可回收的多相催化剂用于在温和条件下有效地将芳烷基硫化物选择性氧化为亚砜。
7. Alcohol-Selective Oxidation in Water under Mild Conditions via a Novel Approach to Hybrid Composite Photocatalysts [O] . Abd Elaal A., Parrino F., Ciriminna R., 2015

机译：新型复合杂化光催化剂在温和条件下水中的醇选择性氧化
8. Thermally Activated Magnesium Oxide as a Selective Deuteration Catalyst under Mild Conditions [R] . Hoq, M. F., Klabunde, K. J. 1986

机译：热活化氧化镁作为温和条件下的选择性氘化催化剂

Emodin as a novel organic photocatalyst for selective oxidation of sulfides under mild conditions

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