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Electrochemical reduction of bulk graphene oxide materials

机译:散装石墨烯氧化物材料的电化学减少

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Electrochemical reduction has been used to prepare graphene materials with one-dimensional (1D) to three-dimensional (3D) architecture. The electron acts as the reducing agent directly during the electrochemical reduction, which gives efficient reduction with the conservation of the original structure of the graphene oxide (GO) materials. It provides a simple method to process the GO nanosheets into designed materials using it in aqueous solution, and with an electrochemical reduction to realise the functional graphene materials. This method avoids using graphene nanosheets as the feedstock which are difficult to dissolve in a solvent, especially at a high concentration. 1D fiber, two-dimensional thin film on glass or poly(ethylene terephthalate) (flat or curved), and 3D graphene sponge have been successfully prepared, and the dynamics of the reduction was also studied. Electrochemical reduction is especially suitable for reducing composites of GO and polymers, a process which can be carried out at room temperature without any chemical reducing agents. A silk fibroin/electrochemically reduced GO (SF/ERGO) composite film was prepared using homogeneous reduction, which showed excellent mechanical properties and electrical conductivity. Electrochemical reduction is a general method to prepare many kinds of graphene materials for a wide range of applications.
机译:电化学还原已用于制备具有一维(1D)至三维(3D)架构的石墨烯材料。在电化学还原过程中,电子用作还原剂,随着石墨烯氧化物(GO)材料的原始结构的守恒提供了有效的降低。它提供了一种简单的方法,可以在水溶液中使用它在设计材料中处理Go nanosheLs,并且具有电化学还原以实现功能性石墨烯材料。该方法避免使用石墨烯纳米片作为难以溶解在溶剂中的原料,尤其是高浓度。 1D纤维,玻璃上的二维薄膜或聚(对苯二甲酸乙二醇酯)(扁平或弯曲),以及3D石墨烯海绵状物和3D石墨烯海绵,还研究了还原的动态。电化学减少特别适用于还原Go和聚合物的复合材料,该方法可以在室温下没有任何化学药物进行的方法。使用均匀还原制备丝素蛋白/电化学减少的GO(SF / ERGO)复合膜,其显示出优异的机械性能和电导率。电化学还原是一种制备多种型石墨烯材料的一般方法,适用于各种应用。

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