An unconventional route to fabricate highly pure α-Al2O3 nanocrystals with tunable surface chemistry based on a semi-aromatic polyamide with pyridine rings as a functional matrix

Zhaopeng Li; Junle Zhang; Peng Fu; Zhe Cui; Xinchang Pang; Minying Liu; Qingxiang Zhao

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An unconventional route to fabricate highly pure α-Al2O3 nanocrystals with tunable surface chemistry based on a semi-aromatic polyamide with pyridine rings as a functional matrix

机译：基于与吡啶环的半芳族聚酰胺基于半芳族聚酰胺制造高纯α-Al2O3纳米晶体的非常规途径，作为吡啶环作为功能基质

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摘要

An unconventional but robust route to fabricate highly pure α-Al _(2) O _(3) colloidal nanocrystals with tunable surface chemistry and dimensions was introduced based on semi-aromatic polyamide (PA6Py) with pyridine rings as a functional matrix. The surface ligands of α-Al _(2) O _(3) nanocrystals can be tuned by choosing different carboxyl-terminated polymers ( e.g. , PS and PEO).

机译：基于半芳族聚酰胺（PA6PY），引入了具有可调谐表面化学和尺寸的高纯α-Al _（2）o _（3）胶体纳米晶体的非常规但坚固的途径。用吡啶环作为功能基质。可以通过选择不同的羧基封端的聚合物（例如PS和PEO）来调节α-Al _（2）Oα（2）Oα（3）纳米晶的表面配体。

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《RSC Advances》 |2016年第83期|共5页
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Zhaopeng Li; Junle Zhang; Peng Fu; Zhe Cui; Xinchang Pang; Minying Liu; Qingxiang Zhao;
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1. An unconventional route to fabricate highly pure alpha-Al2O3 nanocrystals with tunable surface chemistry based on a semi-aromatic polyamide with pyridine rings as a functional matrix [J] . Li Zhaopeng, Zhang Junle, Fu Peng, RSC Advances . 2016,第83期

机译：基于用吡啶环的半芳族聚酰胺制造具有可调谐表面化学的高纯α-Al2O3纳米晶体的非常规途径，作为吡啶环作为功能基质
2. Unconventional Strategy to Anatase TiO2 Nanocrystals with Tunable Surface Chemistry via Liquid Crystalline Polyamides as a Functional Matrix [J] . Zhang Chenxi, Zhang Lingli, You Ning, The journal of physical chemistry, C. Nanomaterials and interfaces . 2017,第48期

机译：通过液晶多酰胺与可调谐表面化学的锐钛矿TiO2纳米晶体作为功能基质的非常规策略
3. Asymmetric Route to Pyridines Bearing a Highly Functionalized 2-Alkyl Substituent by Aziridine Ring-Opening Reactions [J] . Diego Savoia, Giuseppe Alvaro, Romano Di Fabio, The Journal of Organic Chemistry . 2007,第10期

机译：通过氮丙啶开环反应生成具有高度官能化的2-烷基取代基的吡啶的不对称路线
4. Unconventional route to dual-shelled organolead halide perovskite nanocrystals with controlled dimensions surface chemistry and stabilities [O] . Yanjie He, Young Jun Yoon, Yeu Wei Harn, 2019

机译：具有控制尺寸表面化学性质和稳定性的双壳有机卤化铅钙钛矿纳米晶体的非常规途径
5. Asymmetric Route to Pyridines Bearing a Highly Functionalized 2-Alkyl Substituent by Aziridine Ring-Opening Reactions [O] . -1

机译：吡啶的不对称途径含有氮杂萘开环反应的高官能化的2-烷基取代基

An unconventional route to fabricate highly pure α-Al2O3 nanocrystals with tunable surface chemistry based on a semi-aromatic polyamide with pyridine rings as a functional matrix

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