Photoisomerization and optical properties of a subphthalocyanine–azobenzene–subphthalocyanine triad

Maohu Shi; Yue Zhao; Haijun Xu; John Mack; Luan Yin; Xiaoyong Wang; Zhen Shen

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Photoisomerization and optical properties of a subphthalocyanine–azobenzene–subphthalocyanine triad

机译：亚酞菁 - 偶氮苯 - 亚甲酞菁三合会的光硅酸光学性和光学性质

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The synthesis and characterization of a subphthalocyanine–azobenzene–subphthalocyanine triad is reported. Evidence for trans ? cis isomerization of the linking azobenzene moiety is observed in the NMR and optical spectra when the subphthalocyanine rings are used as light-harvesting units. Significantly, a decrease in fluorescence intensity is observed on moving from trans → cis with a recovery in intensity observed on moving back from cis → trans that can be attributed to a change in the rate of non-radiative decay.

机译：据报道了亚酞菁 - 偶氮苯甲酯三胞苷的合成和表征。跨境的证据？当亚酞菁环用作光收获单元时，在NMR和光谱中观察到连接偶氮苯部分的CIS异构化。值得注意地，在从CIS→逆转器中移动的恢复开始，从转换→CIS转移，观察到荧光强度的降低，从而从CIS→逆变，这可能归因于非辐射衰减速率的变化。

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《RSC Advances》 |2016年第75期|共7页
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Maohu Shi; Yue Zhao; Haijun Xu; John Mack; Luan Yin; Xiaoyong Wang; Zhen Shen;
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1. Photoisomerization and optical properties of a subphthalocyanine-azobenzene-subphthalocyanine triad [J] . Shi Maohu, Zhao Yue, Xu Haijun, RSC Advances . 2016,第75期

机译：亚酞菁 - 偶氮苯 - 亚甲酞菁三合会的光硅酸光学性和光学性质
2. Photoisomerization and optical behavior study of a subphthalocyanine-bisazobenzene-subphthalocyanine triad with visible-light response [J] . Shi Maohu, Mack John, Yin Luan, Journal of Materials Chemistry, C. materials for optical and electronic devices . 2016,第33期

机译：具有可见光响应的亚酞菁-双偶氮苯-亚酞菁三联体的光异构化和光学行为研究
3. Synthesis and Properties of Subphthalocyanine–Tetracyanobutadiene–Ferrocene Triads [J] . Alberto Vi?as Mu?oz, Henrik Gotfredsen, Martyn Jevric, The Journal of Organic Chemistry . 2018,第4期

机译：甲酞菁 - 四环丁二烯 - 二茂铁三联烯 - 二茂铁三合会的合成与性能
4. Spectral and optical properties of a new subphthalocyanine dye as a potential optical recording material [C] . Yang Wang, Donghong Gu, Fuxi Gan, International symposium on optical storage . 2001

机译：新甲酞菁染料的光谱和光学性质作为潜在的光学记录材料
5. Stable Boron Subphthalocyanines: A Structure Property Relationship and New Processes for Further Synthetic Study. [D] . Brisson, Emma R. L. 2011

机译：稳定的硼亚酞菁硼：结构性质关系和进一步合成研究的新方法。
6. Synthesis Characterization and Optoelectronic Property of Axial‐Substituted Subphthalocyanines [O] . Dr. Zhuo Li, Bing Wang, Bingbing Zhang, 2020

机译：轴向取代的亚酞菁的合成表征和光电性能
7. Tuning Optical and Electron Donor Properties by Peripheral Thio–Aryl Substitution of Subphthalocyanine: A New Series of Donor–Acceptor Hybrids for Photoinduced Charge Separation [O] . Chandra B. KC, Gary N. Lim, Francis DSouza 2016

机译：通过外周硫代芳基取代亚酞菁调节光学和电子给体性质：用于光诱导电荷分离的新系列供体 - 受体杂种

Photoisomerization and optical properties of a subphthalocyanine–azobenzene–subphthalocyanine triad

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