Synthesis, structure and photochromic properties of hybrid molecules based on fullerene C60 and spiropyrans

A. R. Tuktarov; A. A. Khuzin; A. R. Tulyabaev; O. V. Venidictova; T. M. Valova; V. A. Barachevsky; L. M. Khalilov; U. M. Dzhemilev

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Synthesis, structure and photochromic properties of hybrid molecules based on fullerene C60 and spiropyrans

机译：基于富勒烯C60和螺吡喃的杂化分子的合成，结构和光致变色特性

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The 1,3-dipolar cycloaddition of azomethine ylides to fullerene C _(60) was utilized to perform the synthesis of spiropyran-containing photochromic pyrrolidinofullerenes. It was found that photochromism is observed only for the hybrid compound containing an NO _(2) group in the pyran moiety, whereas the pyrrolidinofullerenes with Cl or F atoms in the spiropyran moiety do not possess photochromism. The photochromic fullerene hybrid is characterized by lower light sensitivity and photodegradation parameters compared to the initial spiropyrans, which can be attributed to reabsorption of activating radiation.

机译：利用氮杂甲酸钠的1,3-双极环加成芳烯C_（60）来进行含螺螺吡喃光致变色吡咯烷的合成。发现仅针对吡喃部分含有NO _（2）基团的杂化化合物观察到光致变色，而螺吡喃部分中的吡咯烷烃与Cl或F原子不具有光致弹。与初始螺丝吡喃相比，光致变色富勒烯杂种的特征在于光敏感性和光降解参数，这可能归因于激活辐射的重吸收。

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《RSC Advances》 |2016年第75期|共5页
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A. R. Tuktarov; A. A. Khuzin; A. R. Tulyabaev; O. V. Venidictova; T. M. Valova; V. A. Barachevsky; L. M. Khalilov; U. M. Dzhemilev;
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1. Synthesis, structure and photochromic properties of hybrid molecules based on fullerene C-60 and spiropyrans [J] . Tuktarov A. R., Khuzin A. A., Tulyabaev A. R., RSC Advances . 2016,第75期

机译：基于富勒烯C-60和螺吡喃的杂化分子的合成，结构和光致变色性能
2. Photocontrolled organic field effect transistors based on the fullerene C60 and spiropyran hybrid molecule [J] . A. R. Tuktarov, R. B. Salikhov, A. A. Khuzin, RSC Advances . 2019,第13期

机译：基于富勒烯C60和螺杂交分子的光控制有机场效应晶体管
3. Synthesis and photochromic properties of hybrid molecules based on fullerene C-60 and 3,3 '-(cyclopent-1-ene-1,2-diyl)bis(5-chloro-2-methylthiophene) [J] . Tuktarov A. R., Akhmetov A. R., Khuzin A. A., Russian Journal of Organic Chemistry . 2017,第6期

机译：基于富勒烯C-60和3,3' - （Cyperopent-1-Ene-1,2-二基）双（5-氯-2-甲基噻吩）的杂化分子的合成与光致变色性质
4. Synthesis and Properties of an Open-Cage Fullerene C60 Derivative Encapsulating a Paramagnetic NO Molecule [C] . Shota Hasegawa, Yoshifumi Hashikawa, Yasujiro Murata 日本化学会春季年会講演予稿集 . 2018

机译：开放式富勒烯C60衍生物的合成与性质包封了顺磁无分子
5. Spectroscopic investigations of the photochemical properties of I. Spiropyran on y zeolite for photochromic applications II. Rhenium(I) bipyridyl tricarbonyl on mesoporous ZSM-5 zeolite and silica for photocatalytic reduction of carbon dioxide [D] . Dubois, Kevin 2013

机译：I. Spiropyran在y沸石上用于光致变色应用的光化学性质的光谱研究II。 ZSM-5分子筛和二氧化硅上联吡啶三羰基tri（I）用于光催化还原二氧化碳
6. Structure based design synthesis and activity studies of small hybrid molecules as HDAC and G9a dual inhibitors [O] . Lanlan Zang, Shukkoor M. Kondengaden, Qing Zhang, 2017

机译：作为HDAC和G9a双重抑制剂的小杂种分子的基于结构的设计合成和活性研究
7. Synthesis, Characterization, and Photochromic Properties of Hybrid Organic-Inorganic Materials Based on Molybdate, DABCO, and Piperazine [O] . -1

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Synthesis, structure and photochromic properties of hybrid molecules based on fullerene C60 and spiropyrans

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