Reversible modulation of the activity of thiourea catalysts with anions: a simple approach to switchable asymmetric catalysis

Giacomo Foli; Cecilia Sasso DElia; Mariafrancesca Fochi; Luca Bernardi

首页> 外文期刊>RSC Advances >Reversible modulation of the activity of thiourea catalysts with anions: a simple approach to switchable asymmetric catalysis

【24h】

Reversible modulation of the activity of thiourea catalysts with anions: a simple approach to switchable asymmetric catalysis

机译：硫脲催化剂与阴离子活性的可逆调节：可切换不对称催化的简单方法

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Leveraging the anion binding properties of thioureas, we show that the activity of known well-performing chiral catalysts can be reduced by coordinating anions ( e.g. chloride) and restored by anion metatheses. Three benchmark enantioselective transformations were successfully studied, demonstrating the reversibility of the activation/deactivation processes.

机译：利用硫脲的阴离子结合特性，我们表明，通过协调阴离子（例如氯化物）可以减少已知性良好的手性催化剂的活性并被阴离子元素恢复。成功研究了三个基准映射转化，证明了激活/停用过程的可逆性。

著录项

来源
《RSC Advances》 |2016年第71期|共5页
作者
Giacomo Foli; Cecilia Sasso DElia; Mariafrancesca Fochi; Luca Bernardi;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Reversible modulation of the activity of thiourea catalysts with anions: a simple approach to switchable asymmetric catalysis [J] . Foli Giacomo, DElia Cecilia Sasso, Fochi Mariafrancesca, RSC Advances . 2016,第71期

机译：硫脲催化剂与阴离子活性的可逆调节：可切换不对称催化的简单方法
2. Physical Organic Study of Structure–Activity–EnantioselectivityRelationships in Asymmetric Bifunctional Thiourea Catalysis: Hints for the Design of New Organocatalysts [J] . Xin Li, Hui Deng, Bo Zhang, Chemistry: A European journal . 2010,第2期

机译：不对称双功能硫脲催化中结构-活性-对映选择性关系的物理有机研究：新型有机催化剂设计的提示
3. Physical Organic Study of Structure–Activity–Enantioselectivity Relationships in Asymmetric Bifunctional Thiourea Catalysis: Hints for the Design of New Organocatalysts [J] . Xin Li Dr., Hui Deng, Bo Zhang, Chemistry - A European Journal . 2010,第2期

机译：不对称双功能硫脲催化中结构-活性-对映选择性关系的物理有机研究：设计新的有机催化剂的提示
4. (Invited) Nanocarbon Catalysts for Reversible Energy Storage and Conversion Via Oxygen Electrocatalysis [C] . Gang Wu Meeting of the Electrochemical Society;International Meeting on Chemical Sensors . 2020

机译：（邀请的）纳米碳催化剂，用于通过氧电催化可逆储能和转化率
5. Chiral thioureas in asymmetric catalysis: From simple to bifunctional [D] . Lalonde, Mathieu Pascal 2008

机译：不对称催化中的手性硫脲：从简单到双功能
6. Mechanism-Guided Development of a Highly Active Bis-Thiourea Catalyst for Anion-Abstraction Catalysis [O] . C. Rose Kennedy, Dan Lehnherr, Naomi S. Rajapaksa, -1

机译：阴离子提取催化高活性双硫脲催化剂的机理指导开发
7. Switching Between Anion-Binding Catalysis and Aminocatalysis with a Rotaxane Dual-Function Catalyst [O] . Eichstaedt, Katarzyna, Jaramillo Garca, Javier, Leigh, David, 2018

机译：用Rotaxane双功能催化剂在阴离子结合催化和氨基催化作用之间切换

Reversible modulation of the activity of thiourea catalysts with anions: a simple approach to switchable asymmetric catalysis

摘要

著录项

相似文献

相关主题

期刊订阅