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Enhancing the mechanical and thermal properties of boron nitride nanoplatelets/elastomer nanocomposites by latex mixing

机译:通过乳胶混合提高氮化硼纳米泊纳米孔/弹性体纳米复合材料的机械和热性能

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Hexagonal boron nitride nanoplatelets (BNNPs) can serve as two-dimensional (2D) fillers for elastomer nanocomposites due to their excellent and intriguing mechanical and thermal properties. Homogeneous and stable dispersion of BNNPs in elastomer is key to successful composite applications. Herein we propose a facile and easily industrialized approach for incorporating fully exfoliated BNNPs with hydroxyl functional groups into elastomer using the latex compounding method. The prepared BNNPs are highly dispersed in various solvents and their size of a few microns preserves their in-plane structure. The environmentally friendly, cost-effective, scalable preparation method proposed shows great potential for advancing the performance of elastomer nanocomposites. Specifically, the incorporation of BNNPs into the elastomer matrix remarkably improved the elastic modulus and tensile strength, even at low loadings; this was ascribed to the enhanced interfacial bonding of the BNNPs with the elastomer matrix. Moreover, well-dispersed BNNPs within the elastomer provided outstanding thermal conductivity and gas permeability.
机译:由于其优异和有趣的机械和热性能,六方硼氮化物纳米片(BNNP)可用作弹性体纳米复合材料的二维(2D)填料。 BNNP在弹性体中的均匀和稳定分散体是成功复合应用的关键。在此,我们提出了一种易于和易于工业化的方法,用于使用乳胶复合方法将全剥离的BNNP与羟基官能团的完全剥离的BNNP掺入弹性体中。制备的BNNP在各种溶剂中高度分散,并且它们的尺寸为几微米保留其面内结构。建议的环境友好,成本效益可扩展的制备方法表现出推进弹性体纳米复合材料性能的巨大潜力。具体地,即使在低负载下,也将BNNP掺入弹性体基质中的弹性模量和拉伸强度显着提高了弹性模量和拉伸强度;这归因于BNNP与弹性体基质的增强界面键合。此外,弹性体内的分散的BNNP良好地提供了出色的导热性和透气性。

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