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Facile fabrication hybrids of TiO2@ZnO tubes with enhanced photocatalytic properties

机译:具有增强的光催化性能的TiO2 @ ZnO管的容易制造杂种

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Hollow nano-tubes of TiO _(2) and TiO _(2) @ZnO hybrids were produced by a facile and mild approach combining an electrospinning technique and soaking method, followed by calcination. During the synthesis process, the electrospinning procedure provides the templates for the fabrication of hollow nano-tubes by producing the PS fibres, which are porous and enable the immobilization of amorphous TiO _(2) through the soaking method. After that, the composite fibers of TiO _(2) /PS and TiO _(2) @ZnO/PS were calcined into pure TiO _(2) and TiO _(2) @ZnO tubes after the complete combustion of organic materials. The samples were then characterized by Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and X-ray diffraction (XRD). Ultimately, the photocatalytic performance of the hybrids was evaluated from the degradation of methylene blue (MB), where they exhibited excellent photocatalytic activity. The proposed mechanism for the enhanced photocatalytic efficiency of the samples is explained at the end of the paper. In principle, the approach to the fabrication of TiO _(2) tubes is demonstrated to be an effective and robust strategy to fabricate long and uniform metal-oxide micro-nano tubes on a large scale.
机译:通过组合静电纺丝技术和浸泡方法的容易和温和的方法产生中空纳米管的TiO _(2)和TiO _(2)@ZnO杂交物,然后通过煅烧方法。在合成过程中,静电纺丝过程通过生产PS纤维来提供用于制造中空纳米管的模板,该纤维是多孔的,使得通过浸泡方法固定无定形TiO_(2)。之后,在完全燃烧有机材料之后,将TiO _(2)/ ps和TiO _(2)和TiO / Ps的复合纤维煅烧成纯TiO _(2)和TiO _(2)@ZnO管。然后通过扫描电子显微镜(SEM),透射电子显微镜(TEM)和X射线衍射(XRD)来表征样品。最终,从亚甲基蓝(MB)的降解中评价杂种的光催化性能,在那里它们表现出优异的光催化活性。在纸张结束时解释了样品的增强光催化效率的提出机制。原则上,制造TiO _(2)管的制造方法是一种有效且稳健的策略,用于在大规模上制造长而均匀的金属氧化物微纳米管。

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