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Hierarchical structured polymers for light-absorption enhancement of silicon-based solar power systems

机译:基于硅的太阳能电力系统的吸光增强层次结构化聚合物

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Light-absorption enhancement of silicon (Si)-based solar power systems ( i.e. , solar modules) is reported by employing a ultraviolet-curable polymer ( i.e. , NOA63) film integrated with a hierarchical structure (HS) consisting of nanonipples on micropyramids onto the PET cover as a protective antireflection (PAR) layer. The HS-patterns can be easily transferred from Si molds with the HS via poly-dimethylsiloxane stamps by soft lithography. The HS-NOA63 film increases the total and diffuse transmittances of the bare polyethylene terephthalate (PET), simultaneously, at wavelengths of 380–1100 nm, thus resulting in the reduced surface reflection ( i.e. , lower solar weighted reflectance ( R _(sw) ) of 6.1%) and the strong light scattering ( i.e. , much higher average haze ratio ( H _(avg) ) of 90.7%) compared to the bare PET ( i.e. , R _(sw) = 11.7% and H _(avg) = 6.9%). Consequently, the Si solar modules with the HS-NOA63 PAR layer of the PET cover exhibit a superior solar power generation in a wide incident angle range (0–70°) of solar irradiance, especially, showing a relative increment percentage of 6.3% in power conversion efficiency (PCE) at 0° ( i.e. , from PCE = 13.46 to 14.3%). Also, it has a superhydrophobic surface with a high water contact angle of 150°, which leads to a self-cleaning ability to protect Si solar modules from being polluted by water droplets and dust particles in outdoor applications.
机译:通过采用与分层结构(HS)集成的紫外线固化的聚合物(即NOA63)薄膜组成的微嘧啶上的分层结构(即,NOA63)薄膜来报告硅(SI)的太阳能系统(即,太阳能模块)的吸光吸收增强。 PET盖作为保护抗反射(PAR)层。通过软光刻可以容易地通过聚二甲基硅氧烷标记从Si模具容易地从Si模具转移到HS。 HS-NOA63膜同时增加裸聚乙烯对苯二甲酸乙二醇酯(PET)的总和漫射透射率,在380-1100nm的波长下,从而导致表面反射减小(即,较低的太阳加权反射(R _(SW)与裸宠物相比)= 6.9%)。因此,具有HS-NOA63 PAR层的Si太阳能模块PET覆盖层在太阳辐照度的宽入射角范围(0-70°)中具有出色的太阳能发电,尤其是6.3%的相对增量百分比功率转换效率(PCE)在0°(即,从PCE = 13.46至14.3%)。而且,它具有超疏水表面,具有150°的高水电接触角,这导致自清洁能力保护Si太阳能模块免受液滴和室外应用中的粉尘颗粒污染的能力。

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