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N-doped zeolite-templated carbon as a metal-free electrocatalyst for oxygen reduction

机译:N-掺杂的沸石 - 模板碳作为无金属电催化剂,用于氧还原

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Nitrogen-doped, zeolite-templated carbon was synthesized using aqueous acetonitrile as a nitrogen-containing carbon source, and beta zeolite as a template. The carbon had a three-dimensionally ordered microporous structure with a large surface area, which consisted of sp ~(2) -carbon. The nitrogen content was approximately 4 wt%. In the electrocatalytic oxygen reduction reaction, the nitrogen-doped zeolite-templated carbon showed a notably high current density and a positive onset potential as compared to nitrogen-doped reduced graphene oxide. The surface of this carbon also had a lower work function than that of planar graphene. The high catalytic performance with the low work function of this carbon seems to come from a curved graphene-like framework structure containing nitrogen.
机译:使用乙腈水溶液作为含氮的碳源和β沸石作为模板合成氮掺杂的沸石模板碳。碳的三维有序的微孔结构具有大表面积,由Sp〜(2) - 碳。氮含量约为4wt%。在电催化氧还原反应中,与氮气掺杂的氧化物相比,氮掺杂的沸石镀碳碳显示出显着的高电流密度和正发病电位。该碳的表面也具有比平坦石墨烯的功函数较低。具有该碳的低功函数的高催化性能似乎来自含有氮的弯曲石墨烯样框架结构。

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