Nickel(ii)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for Heck and Henry reactions

Ana P. C. Ribeiro; Yauhen Yu Karabach; Luísa M. D. R. S. Martins; Abdallah G. Mahmoud; M. Fátima C. Guedes da Silva; Armando J. L. Pombeiro

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Nickel(ii)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for Heck and Henry reactions

机译：镍（II）-2-氨基-4-烷氧基-1,3,5-三氮杂化加入复合物作为Heck和Henry反应的催化剂

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Nickel( II )-triazapentadienate complexes, [Ni(tap) _(2) ], are synthesized and found to act as catalysts in the Heck reaction of deactivated aryl halides. The use of room-temperature ionic liquids instead of organic solvents allows easy separation of the catalyst from the products and substrates. The synthesized complexes also catalyse the Henry reaction of benzaldehydes with nitroethane, at 25 °C, leading to the corresponding nitroalkanols with diastereoselectivity in favour of the anti isomer.

机译：合成镍（II） - 三氮杂化络合物，[Ni（Tap）_（2）]，发现在失活芳基卤化物的静脉反应中作为催化剂。使用室温离子液体代替有机溶剂，可以容易地将催化剂与产物和基材分离。合成的配合物还催化苯甲醛与硝基甲烷的亨利反应，在25℃下，导致相应的硝基烷醇，具有反异构体的非对映选择性。

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《RSC Advances》 |2016年第35期|共5页
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Ana P. C. Ribeiro; Yauhen Yu Karabach; Luísa M. D. R. S. Martins; Abdallah G. Mahmoud; M. Fátima C. Guedes da Silva; Armando J. L. Pombeiro;
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1. Nickel(II)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for Heck and Henry reactions [J] . Ribeiro Ana P. C., Karabach Yauhen Yu, Martins Luisa M. D. R. S., RSC Advances . 2016,第35期

机译：镍（II）-2-氨基-4-烷氧基-1,3,5-三氮杂化加入复合物作为Heck和Henry反应的催化剂
2. Synthesis and Reactivity of Palladium and Nickel beta-Diimine Complexes:Application as Catalysts for Heck,Suzuki,and Hiyama Coupling Reactions [J] . Doris Domin, David Benito-Garagorri, Kurt Mereiter, Organometallics . 2005,第16期

机译：钯和镍-β-二胺镍配合物的合成和反应性：作为Heck，Suzuki和Hiyama偶联反应的催化剂
3. Synthesis and characterization of palladium(II) and platinum(II) metal complexes with iminophosphine ligands: X-ray crystal structures of platinum(II) complexes and use of palladium(II) complexes as pre-catalysts in Heck and Suzuki cross-coupling reactions [J] . Haleden Chiririwa, Freeman Ntuli, Edison Muzenda Transition Metal Chemistry . 2013,第4期

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4. MOLECULAR-PALLADIUM COMPLEXES COVALENTLY BONDED TO GRAPHENE AS CATALYSTS IN THE HECK CROSS-COUPLING REACTION [C] . Laura Fernandez-Garcia, Matias Blanco, Zoraida Gonzalez World Conference on Carbon . 2016

机译：分子 - 钯配合物在Heck交叉偶联反应中共价键合至石墨烯作为催化剂
5. I. Nickel-Exchanged Zincosilicate Catalysts for the Oligomerization of Propylene and II. Organic SDA-Free Catalysts for the Methanol-to-Olefins Reaction [D] . Deimund, Mark A. 2015

机译：I.镍交换的丙炔硅酸盐催化剂，用于丙烯和II的低聚。用于甲醇 - 烯烃反应的有机SDA的催化剂
6. A Broadly Applicable Strategy for Entry into HomogeneousNickel(0) Catalysts from Air-Stable Nickel(II) Complexes [O] . Eric A. Standley, StaceyJ. Smith, †, -1

机译：进入同质化的广泛应用策略空气稳定的镍（II）配合物的镍（0）催化剂
7. Nickel (ii)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for heck and henry reactions [O] . Ribeiro, Ana P. C., Karabach, Yauhen Yu, Martins, Luisa M. D. R. S, 2016

机译：（ii）-2-氨基-4-烷氧基-1,3,5-三氮杂五乙二酸镍配合物作为heck和henry反应的催化剂

Nickel(ii)-2-amino-4-alkoxy-1,3,5-triazapentadienate complexes as catalysts for Heck and Henry reactions

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