A metal-free tandem ring-opening/ring-closing strategy for the heterocyclic conversion of benzoxazin-4-ones to oxazolines

Nomula Rajesh; Banala Manisha; Jala Ranjith; Palakodety Radha Krishna

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A metal-free tandem ring-opening/ring-closing strategy for the heterocyclic conversion of benzoxazin-4-ones to oxazolines

机译：无金属串联环开/环关闭策略，用于苯并恶唑嗪-4-氧化锆的杂环转化率

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A facile metal-free tandem ring-opening/ring-closing strategy was developed for the synthesis of oxazolines in good to excellent reaction yields under mild reaction conditions. This reaction essentially describes a novel tool for the heterocyclic conversion of benzoxazin-4-ones to 2,5-disubstituted oxazolines directly in one-pot.

机译：在轻度反应条件下，为良好的反应产率合成恶唑啉含量，开发了一种容易的无金属串联环开/环闭策略。该反应基本上描述了直接在单罐中直接苯并恶化-4-二苯并嗪-4-二苯并二取代的恶唑啉的新型工具。

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《RSC Advances》 |2016年第8期|共7页
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Nomula Rajesh; Banala Manisha; Jala Ranjith; Palakodety Radha Krishna;
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1. A metal-free tandem ring-opening/ring-closing strategy for the heterocyclic conversion of benzoxazin-4-ones to oxazolines [J] . Rajesh Nomula, Manisha Banala, Ranjith Jala, RSC Advances . 2016,第8期

机译：无金属串联环开/环关闭策略，用于苯并恶唑嗪-4-氧化锆的杂环转化率
2. Versatile Tandem Ring-Opening/Ring-Closing Metathesis Polymerization: Strategies for Successful Polymerization of Challenging Monomers and Their Mechanistic Studies [J] . Hyeon Park, Eun-Hye Kang, Laura Mueller, Journal of the American Chemical Society . 2016,第7期

机译：多功能串联开环/闭环易位聚合：具有挑战性的单体成功聚合的策略及其机理研究
3. One-Pot Tandem Ring-Opening and Ring-Closing Metathesis Polymerization of Disubstituted Cyclopentenes Featuring a Terminal Alkyne Functionality [J] . Podiyanachari Santhosh Kumar, Moncho Salvador, Brothers Edward N., Macromolecules . 2020,第11期

机译：二取代环戊烯酮的单壶串联开环和闭合复分解聚合，具有终端炔烃功能
4. Electrochemically Induced Ring-Closing and Ring-Opening Reactions of Photochromic Dithienylalkenes [C] . Andrea Peters, Neil R.Branda The Meeting of the Electrochemical Society . 2003

机译：电化学诱导光致变色的闭合和开环反应光致变色二烯烯
5. Metal-free Photoredox-mediated Ring-opening Metathesis Polymerization Methods and Scope [D] . Pascual, Laura M. M. 2018

机译：无金属的光氧化还原介导的开环复分解聚合方法和范围
6. Regioselective semi-synthesis of 6-isomers of 58-O-dimethyl ether of shikonin derivatives via an ‘intramolecular ring-closing/ring-opening’ strategy as potent anticancer agents [O] . Li Zhou, Xu Zhang, Wen Zhou 2017

机译：通过分子内闭环/开环策略作为有效的抗癌药对紫草素衍生物的58-O-二甲基醚的6个异构体进行区域选择性半合成
7. Novel tandem ring-opening/ring-closing metathesis reactions of functionalized cyclohexenoids derived from (−)-alpha-pinene [O] . Mehta Goverdhan, Nandakumar Jayakrishnan 2002

机译：从（-）-α-pine烯衍生的功能化环己烯类化合物的新型串联开环/闭环易位反应

A metal-free tandem ring-opening/ring-closing strategy for the heterocyclic conversion of benzoxazin-4-ones to oxazolines

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