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The effect of the support structure on catalytic activity: a case study on hollow and solid MoO3/SiO2

机译:载体结构对催化活性的影响:中空和固体MOO3 / SiO2的案例研究

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Hollow and solid silica nanospheres inlaid with multiple MoO _(3) nanoclusters are obtained by a reverse microemulsion method. Characterization is carried out based on transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma-optical emission spectrometry (ICP-OES) and N _(2) sorption measurements. Their catalytic activity towards acetalization of benzaldehyde was compared. The results showed that the hollow nanocomposite outperformed the solid counterpart. The enhancement of the hollow structure can be attributed to its bigger surface area, shorter pore channels and thus less travelling blockage.
机译:用反向微乳液法测定镶嵌多个MOO _(3)纳米蛋白的中空和固体二氧化硅纳米球。表征基于透射电子显微镜(TEM),高分辨率透射电子显微镜(HRTEM),X射线光电子能谱(XPS),电感耦合等离子体光发射光谱(ICP-OES)和N _(2)吸附测量。比较了它们对苯甲醛的缩略甲醛的催化活性。结果表明,中空纳米复合材料优于固体对应物。中空结构的增强可以归因于其更大的表面积,较短的孔径,因此较少的行驶堵塞。

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