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Preparing mono-dispersed liquid core PDMS microcapsules from thiol–ene–epoxy-tailored flow-focusing microfluidic devices

机译:从硫醇 - 环氧树脂定制的流量聚焦微流体装置中制备单分散的液体核心PDM微胶囊

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An applied dual-cure system based on thiol–ene and thiol–epoxy “click chemistry” reactions was proved to be an extremely effective and easy to use tool for preparing microfluidic chips, thereby allowing for precise control over material properties and providing the possibility of covalently bonding chip wafers. Different thiol–ene–epoxy-based polymer compositions were tested with the help of DSC and ATR FTIR, in order to investigate their physical and chemical properties. Water contact angles were determined, thus verifying the high efficiency and selectivity of the chemical surface modification of compositions in relation to high hydrophilicity and hydrophobicity. An obtained microfluidic device was subsequently used in order to produce PDMS microcapsules of very narrow size distribution and which contained various common liquids, such as water and ethanol, as well as an ionic liquid 2-hydroxyethylammonium formate.
机译:被证明,基于硫醇-EnOE和硫醇 - 环氧树脂“反应的应用双固化系统是一种非常有效且易于使用的用于制备微流体芯片的工具,从而允许精确地控制材料特性并提供可能性共价键合芯片晶片。在DSC和ATR FTIR的帮助下测试不同的硫醇-eEE-环氧基的聚合物组合物,以研究其物理和化学性质。确定水接触角,从而验证了与高亲水性和疏水性的组合物的化学表面改性的高效率和选择性。随后使用获得的微流体装置,以产生非常窄的尺寸分布的PDMS微胶囊,并且含有各种常见的液体,例如水和乙醇,以及离子液体2-羟乙基甲酸酯。

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