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Microstructure and Properties of Polytetrafluoroethylene Composites Modified by Carbon Materials and Aramid Fibers

机译:用碳材料和芳族纤维改性聚四氟乙烯复合材料的微观结构和性质

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Polytetrafluoroethylene (PTFE) is polymerized by tetrafluoroethylene, which has high corrosion resistance, self-lubrication and high temperature resistance. However, due to the large expansion coefficient, high temperature will gradually weaken the intermolecular bonding force of PTFE, which will lead to the enhancement of permeation absorption and the limitation of the application range of fluoroplastics. In order to improve the performance of PTFE, the modified polytetrafluoroethylene, filled by carbon materials and aramid fiber with different scales, is prepared through the compression and sintering. Moreover, the mechanical properties and wear resistance of the prepared composite materials are tested. In addition, the influence of different types of filler materials and contents on the properties of PTFE is studied. According to the experiment results, the addition of carbon fibers with different scales reduces the tensile and impact properties of the composite materials, but the elastic modulus and wear resistance are significantly improved. Among them, the wear rate of 7 μm carbon fiber modified PTFE has decreased by 70%, and the elastic modulus has increased by 70%. The addition of aramid fiber filler significantly reduces the tensile and impact properties of the composite, but its elastic modulus and wear resistance are significantly improved. Among them, the wear rate of the modified composite material with 3% alumina particles and 5% aramid pulp decreased by 68%, and the elastic modulus increased by 206%.
机译:聚四氟乙烯(PTFE)是由四氟乙烯,其具有高的耐腐蚀性,自润滑性及耐高温聚合。然而,由于大的膨胀系数,高温会逐渐减弱PTFE的分子间结合力,这将导致渗透吸收的增强和氟塑料的应用范围的限制。为了提高PTFE,改性聚四氟乙烯的性能,由碳材料和具有不同比例的芳族聚酰胺纤维填充,通过压缩和烧结制备的。此外,所制备的复合材料的机械性能和耐磨损性进行了测试。此外,不同类型的填充材料和PTFE的特性的内容的影响进行了研究。根据实验结果,添加碳纤维的不同尺度降低了复合材料的拉伸和冲击性能,但弹性模量和耐磨损性都显著提高。其中,7微米的碳纤维的磨损率改性PTFE已下降70%,而弹性模量增加了70%。加入芳族聚酰胺纤维填料的显著降低了复合材料的拉伸和冲击性能,但它的弹性模量和耐磨损性都显著提高。其中,用3%的氧化铝颗粒和5%芳族聚酰胺浆的改性复合材料的磨损率降低了68%,而弹性模量增加了206%。

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