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首页> 外文期刊>Atmospheric Chemistry and Physics Discussions >Formation and growth of atmospheric nanoparticles in the eastern Mediterranean: results from long-term measurements and process simulations
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Formation and growth of atmospheric nanoparticles in the eastern Mediterranean: results from long-term measurements and process simulations

机译:地中海东部大气纳米粒子的形成和生长:长期测量和过程模拟的结果

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Atmospheric new particle formation (NPF) is a common phenomenon all over the world. In this study we present the longest time series of NPF records in the eastern Mediterranean region by analyzing 10 years of aerosol number size distribution data obtained with a mobility particle sizer. The measurements were performed at the Finokalia environmental research station on Crete, Greece, during the period June 2008–June 2018. We found that NPF took place on 27% of the available days, undefined days were 23% and non-event days 50%. NPF is more frequent in April and May probably due to the terrestrial biogenic activity and is less frequent in August. Throughout the period under study, nucleation was observed also during the night. Nucleation mode particles had the highest concentration in winter and early spring, mainly because of the minimum sinks, and their average contribution to the total particle number concentration was 8%. Nucleation mode particle concentrations were low outside periods of active NPF and growth, so there are hardly any other local sources of sub-25nm particles. Additional atmospheric ion size distribution data simultaneously collected for more than 2 years were also analyzed. Classification of NPF events based on ion spectrometer measurements differed from the corresponding classification based on a mobility spectrometer, possibly indicating a different representation of local and regional NPF events between these two measurement data sets. We used the MALTE-Box model for simulating a case study of NPF in the eastern Mediterranean region. Monoterpenes contributing to NPF can explain a large fraction of the observed NPF events according to our model simulations. However the adjusted parameterization resulting from our sensitivity tests was significantly different from the initial one that had been determined for the boreal environment.
机译:大气新粒子形成(NPF)是世界各地的常见现象。在这项研究中,我们通过分析使用迁移粒子Sizer获得的10年的气溶胶数尺寸分布数据,提出了东部地中海地区的最长时间系列NPF记录。在2018年6月至6月期间,在克里特岛的Finokalia环境研究站点进行了测量。我们发现NPF于27%的可用日内进行,未定义的日子为23%,非事件日为50% 。 NPF在4月份更频繁,可能是由于陆地生物活动,8月份不太频繁。在整个研究中,在夜间也观察到成核。成核模式颗粒在冬季和早春的浓度最高,主要是因为最小的水槽,它们对总粒子数浓度的平均贡献为8%。成核模式颗粒浓度在活性NPF和生长的外部较低,因此几乎没有任何其他局部亚25nm颗粒来源。还分析了额外的大气离子尺寸分布数据超过2年。基于离子光谱仪测量的NPF事件的分类与基于移动光谱仪的相应分类不同,可能指示这两个测量数据集之间的本地和区域NPF事件的不同表示。我们使用了Malte-Box模型来模拟东部地中海地区NPF的案例研究。贡献对NPF的单调人可以根据我们的模型仿真解释观察到的NPF事件的大部分。然而,由我们的敏感性测试产生的调整后的参数化与针对北方环境确定的最初的参数化有很大差异。
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