The aerosol liquid water (ALW) content?(ALWC), an important component of atmospheric particles, has a significant effect on atmospheric optical properties, visibility and multiphase chemical reactions. In this study, ALWC is determined from aerosol hygroscopic growth factor (GF) and particle number size distribution?(PNSD) measurements and is also simulated by ISORROPIA?II, a thermodynamic equilibrium model, with measured aerosol chemical composition data taken at an urban site in Beijing from 8?November to 15?December?2017. Rich measurements made during the experiment concerning virtually all aerosol properties allow us not only to derive the ALWC but also to study the contributions by various species for which little has been done in this region. The simulated ALWC including the contribution of organics and the calculated ALWC are highly correlated (coefficient of determination R2=0.92). The ALWC contributed by organics?(ALWCOrg) accounts for 30?%±22?% of the total ALWC during the sampling period. These results suggest a significant contribution of organics to ALWC, which is rather different from previous studies that showed negligible contributions by organics. Our results also show that ALWC correlates well with the mass concentrations of sulfate, nitrate, and secondary organic aerosols?(SOAs) (R2=0.66, 0.56 and?0.60, respectively). We further noted that accumulation mode particles play a key role in determining ALWC, dominating among all the aerosol modes. ALWC is an exponential function of ambient relative humidity?(RH), whose strong diurnal variation influence the diurnal variation of ALWC. However, there is a 3h lag between the extremes of ALWC and RH values, due to the diurnal variations in PNSD and aerosol chemical composition. Finally, a case study reveals that ALWCOrg?plays an important role in the formation of secondary aerosols through multiphase reactions at the initial stage of a heavy-haze episode.
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