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Preparation of MOF Derived Zn-Co-C Composite as Anode for Lithium-ion Batteries

机译:锂离子电池阳极的制备MOF衍生Zn-Co-C复合材料

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This paper focuses on the preparation of hollow mixed metal oxide materials by means of mixed metalatom doping. In this paper, the hollow core-shell structure Zn-Co-MOFs material was prepared byhydrothermal method, calcined into Zn-Co-C material, and its conductivity and electrochemicalperformance were improved on the basis of retaining hollow core-shell channel structure. Hollow coreshell structure to avoid direct contact with the electrode materials and electrolyte, reduce theelectrolyte decomposition, a loop to form porous channel structure, shorten the lithium ion diffusionpath and improve the lithium storage capacity, core-shell structure ACTS as a skeleton structure,effectively relieve internal stress changes, the structure of the electrode material volume change anddestruction, reduce capacity attenuation. The Zn-Co-C composite has a discharge specific capacity of1749mAh g-1in the first coil and a maximum coulomb efficiency of 99.8%. At 200 mA g-1currentdensity, the reversible capacity is up to 704mAh g-1at 200 cycles, and the multiplier and impedanceare also excellent.
机译:本文侧重于通过混合金属掺杂制备中空混合金属氧化物材料。在本文中,将中空核 - 壳结构Zn-Co-Mofs材料制备用水液法制备,煅烧成Zn-Co-C材料,并在保持中空芯壳通道结构的基础上提高了其电导率和电化学性能。空心冠状孔结构以避免与电极材料和电解质直接接触,降低电解质分解,环形成多孔通道结构,缩短锂离子漫射路径,提高锂蓄电池,核心 - 壳结构用作骨架结构,有效缓解内应力变化,电极材料体积变化的结构变化,降低了容量衰减。 Zn-Co-C复合材料的放电比容量为1749mAhg-1,最大线圈和最大库仑效率为99.8%。在200 mA g-1currentdenty,可逆容量高达704mAh g-1at 200循环,乘法器和阻抗也优异。

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