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CoMoO4?Supported by N-doped Carbon Derived from ZIF-67 as a Novel Electrode Material for High Performance Supercapacitors

机译:COMO4?由ZIF-67的N掺杂碳支撑为高性能超级电容器的新型电极材料

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ZIF-67 derivatives show promising applications in energy storage owing to their high surface area andexcellent electrochemical performance. In this work, an N-doped carbon-coated CoMoO4 nanoparticle(CMO@NC) polyhedron was prepared by hydrothermal treatment and calcination. The structural andmorphological properties of the obtained samples were measured by X-ray diffraction (XRD), scanningelectron microscopy (SEM) and N2 adsorption/desorption isotherms. In terms of electrochemicalperformance, CMO@NC exhibits a remarkable specific capacitance of 267.3 F g-1at 0.5 A g-1.Moreover, a hybrid supercapacitor device with CMO@NC as the positive electrode material and activecarbon (AC) as the negative electrode material was observed to achieve a specific capacitance of 114 Fg-1at 0.5 A g-1, with a stable operational voltage of 1.5 V and a maximum energy density of 35.4 Whkg-1at a power density of 1041 W kg-1. The specific capacitance retention can reach up to 82.4 % after5000 cycles, as determined by GCD measurements, indicating outstanding cycling stability and potentialapplication prospects in supercapacitors.
机译:由于其高表面积和电化学性能,ZIF-67衍生物在储能中显示了有希望的应用。在这项工作中,通过水热处理和煅烧制备了一种N掺杂的碳涂覆的COMO4纳米颗粒(CMO @ NC)多合金。通过X射线衍射(XRD),扫描电子显微镜(SEM)和N 2吸附/解吸等温线测量所得样品的结构和晶二文性质。在电化学性能方面,CMO @ NC表现出显着的比电容为267.3f G-1AT 0.5A G-1.MOREOVER,一种具有CMO @ NC的混合超级电容器装置,作为正极材料和活性癸镁(AC)作为负极材料观察到实现114 FG-1AT 0.5A G-1的特定电容,稳定的操作电压为1.5V,最大能量密度为35.4 WHKG-1AT的功率密度为1041WKG-1。通过GCD测量确定的特定电容保留可达到高达82.4%的5000次循环,表明超级电容器中出色的循环稳定性和潜在应用前景。

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