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Effects of Pressure Evolution on the Decrease in the Capacity of Lithium-Ion Batteries

机译:压力演化对锂离子电池容量降低的影响

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External mechanical pressure can affect the cycle life of lithium-ion battery. In this paper, theevolution process of the mechanical pressure that a lithium-ion battery was subjected to duringapproximately 3000 cycles under the fixed constraint was studied through charge-discharge cyclingtests of a lithium-ion battery. The effect of external pressure on battery aging in the late cycle stagewas explored through SEM and incremental capacity analysis (ICA). In addition, three groups ofcomparative experiments, including a rigid constraint, an elastic silicone pad constraint and a springconstraint, were set up to explore the influence of different constraint schemes on battery cycle life.The experimental results showed that the mechanical pressure increased due to the aging of the batteryunder the fixed constraint, which could cause the anode material of the battery to crack. In thecomparative experiment, the capacity decrease rate of the spring compression constraint scheme was5.13% and 6.17% lower than those of the other two groups. The ohmic resistance increase rate was8.67% and 12.36% lower than those of the other two groups, and the coulombic efficiency of thespring constraint remained good in the late stage of the cycle. Therefore, the spring constraint schemecan maximize the positive effect of external pressure on lithium-ion batteries by maintaining arelatively stable external pressure. The results presented in this paper have a certain guidingsignificance for the design of the battery pack.
机译:外部机械压力会影响锂离子电池的循环寿命。在本文中,通过锂离子电池的电荷放电循环研究了在固定约束下进行锂离子电池在固定约束下进行3000个循环的机械压力的分析过程。通过SEM和增量容量分析探讨了外部压力对电池老化的影响(ICA)。此外,设立了三组不合规结构,包括刚性约束,弹性硅胶焊盘约束和弹簧混合物,以探讨不同约束方案对电池循环寿命的影响。实验结果表明,由于所造成的机械压力增加固定约束的电池老化,可能导致电池的阳极材料裂纹。在Checomparative实验中,弹簧压缩约束方案的容量降低率为5.13%,低于其他两组的5.13%和6.17%。欧姆抵抗率增加到8.67%,比其他两组的速度低为8.67%和12.36%,并且在循环的后期阶段,这种约束的库仑效率仍然良好。因此,弹簧约束模式通过维持竞争性稳定的外部压力,最大化外部压力对锂离子电池的正效应。本文提出的结果对电池组的设计具有一定的指导性。

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