首页> 外文期刊>International Journal of Electrochemical Science >A novel Molecularly Imprinted Sensor based on Gold Nanoparticles/Reduced Graphene Oxide/Single-Walled Carbon Nanotubes Nanocomposite for the Detection of pefloxacin
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A novel Molecularly Imprinted Sensor based on Gold Nanoparticles/Reduced Graphene Oxide/Single-Walled Carbon Nanotubes Nanocomposite for the Detection of pefloxacin

机译:基于金纳米颗粒/氧化石墨烯/单壁碳纳米管纳米复合物检测Pefloxacin的新型分子印迹传感器

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A molecularly imprinted electrochemical sensor was developed for the detection of pefloxacin. Themolecularly imprinted polymer (MIP) was prepared via electrodeposition on the surface of a goldnanoparticles/reduced graphene oxide/single-walled carbon nanotubes modified glass carbon electrodeby incorporation of pefloxacin as a template molecule during the electrochemical polymerization of ophenylenediamine. The namocomposite of gold nanoparticals/reduced graphene oxide/single-walledcarbon nanotubes was obtained by one-step electrochemical reduction. Differential pulse voltammogram(DPV) showed a linear pefloxacin concentration range from 5.0 × 10-7 mol/L to 2.0 × 10-5 mol/L, andthe detection limit was 1.6 × 10-8 mol/L. The sensor also showed high selectivity, stability andreproducibility. Moreover, the sensor was successfully applied in the analysis of actual milk sampleswith satisfactory recovery rates.
机译:开发了一种分子印迹电化学传感器用于检测Pefloxacin。通过电沉积在金属基瓶里/较低的石墨烯氧化物/单壁碳纳米管的表面上通过电沉积来制备分子压印的聚合物(MIP),该玻璃碳电极的改性玻璃碳电极由Pefloxacin的掺入甲苯二胺的电化学聚合期间的模板分子。通过一步电化学还原获得金纳米纳米族颗粒/还原的氧化石墨烯/单壁碳纳米管的Namococite。差分脉冲伏安图(DPV)显示线性Pefloxacin浓度范围为5.0×10-7 mol / L至2.0×10-5 mol / L,检测限为1.6×10-8mol / L.该传感器还显示出高选择性,稳定性和再生产性。此外,传感器成功地应用于令人满意的恢复速率的实际牛奶样品。

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