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A study of micro structural, magnetic and electrical properties of La-Co-Sm nanoferrites (LCSF) synthesized by sol-gel method

机译:溶胶 - 凝胶法合成的La-Co-SM纳米铁(LCSF)微结构,磁性和电性能研究

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A Lanthanum (La3 ) doped Samarium-Cobalt nanoferrites (La_x,Co_0.2,Sm_0.2,Fe_(2-x) O_4, where x=0.0,0.5,1.0) have been synthesized by sol-gel method in citrate media. Obtained spinal ferrites micro structure properties have been investigated by XRD, FTIR, SEM-EDX, and TEM-SAED techniques. All the samples are nano in size with significant hysteresis. Micro structural analysis by XRD confirms the obtained samples showing the single phase cubic spinal structures with an average crystal size found from 12 nm to 25 nm, while the average particles sizes identified from TEM analysis are ranging from 21.5nm-26.8 nm (~23.4nm) and from 20.5 nm to 28(~26.4nm) nm for x=0.5,1.0. The lattice parameter found to be a= 8.402, 8.423, 8.467? for the respective values of x= 0.0, 0.05, and 1.0. Electrical properties show increase in dc resistivity with increase in La3 ion concentration. Finally, it was concluded that the doping of Lanthanum ion (La3 ) in the ferrites structure is found to influencing the structural and electrical properties without scarifying the ferromagnetic character.
机译:镧(镧)掺杂有由溶胶 - 凝胶法在柠檬酸盐介质中合成钐 - 钴纳米铁氧体(其中x = 0.0,0.5,1.0 La_x,Co_0.2,Sm_0.2,Fe_(2-X)O_4,)。获得脊椎铁氧体微结构性质已通过X射线衍射,红外光谱,SEM-EDX,和TEM-SAED技术调查。所有样品是纳米大小,有显著的滞后。通过XRD微结构分析证实示出单相立方脊柱结构具有平均晶体尺寸为12纳米至25纳米的发现,得到的样本,而平均颗粒尺寸从TEM的分析,鉴定是范围从21.5nm-26.8纳米(〜23.4nm ),并从20.5纳米至28(〜26.4nm)纳米对于x = 0.5,1.0。晶格参数发现是= 8.402,8.423,8.467?为X = 0.0,0.05和1.0的相应值。电特性显示出与在镧离子浓度的增加增加直流电阻率。最后,得出的结论是镧离子(镧)在铁氧体结构的掺杂被发现不会牺牲铁磁字符影响的结构和电性能。

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