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Effect of Environmental Factors on Hydrogen Absorption into Steel Sheet under a Wet-dry Cyclic Corrosion Condition

机译:环境因素对湿润环状腐蚀条件下钢板氢吸收的影响

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The effects of temperature and chloride deposition on hydrogen absorption into steel were evaluated during wet/dry cyclic corrosion using a temperature-compensated hydrogen absorption monitoring system based on the electrochemical hydrogen permeation method. Hydrogen absorption into steel was detected through the measurement of hydrogen permeation currents during the wet periods under the wet/dry cyclic corrosion. The enhancement of hydrogen absorption was mainly caused by the changes in the solution chemistry during the wetting and drying periods, with a decrease in pH due to the hydrolysis reaction of Fe~(3+) at high Cl~(?) concentration. Hydrogen absorption into steel increased with increasing temperature and chloride deposition. The reasons for the increment of hydrogen absorption are considered that enhancement of the hydrogen evolution reaction with temperature and that the corrosion potential shifted to less noble by increase in the electrolyte thickness with increasing chloride deposition. Based on these results, the amount of absorbed hydrogen map effected by these factors under atmospheric corrosion environment was described.
机译:使用基于电化学氢渗透法的温度补偿氢吸收监测系统,评估温度和氯化物沉积对氢吸收到钢中的氢吸收的影响。通过测量湿/干循环腐蚀下的湿时段期间氢渗透电流检测氢吸收钢。氢吸收的增强主要是由于在润湿和干燥时期的溶液化学的变化引起的,由于Fe〜(3+)在高Cl〜(α)浓度下的水解反应,pH值降低。随着温度和氯化物沉积的增加,氢吸收成钢增加。氢吸收的增量的原因被认为是通过随着氯化物沉积的增加,通过增加电解质厚度随着电解质厚度的增加而增强氢进化反应的增强,并且腐蚀电位通过电解质厚度增加而变化至更高的惰性。基于这些结果,描述了在大气腐蚀环境下由这些因素进行的吸收氢图的量。

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